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trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ(2) N (3),O (4)]manganese(II)
In the title compound, [Mn(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], synthesized by hydrothermal reaction, the Mn(II) ion lies on an inversion centre and displays a distorted octahedral coordination geometry defined by the two imidazole N atoms and two carboxylate O atoms of the two trans-standing chelate...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959396/ https://www.ncbi.nlm.nih.gov/pubmed/21201031 http://dx.doi.org/10.1107/S1600536808029073 |
Sumario: | In the title compound, [Mn(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], synthesized by hydrothermal reaction, the Mn(II) ion lies on an inversion centre and displays a distorted octahedral coordination geometry defined by the two imidazole N atoms and two carboxylate O atoms of the two trans-standing chelate ligands, and two O atoms of the water molecules. A two-dimensional supramolecular architecture is formed via N—H⋯O, O—H⋯N and O—H⋯O hydrogen-bonding interactions. |
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