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trans-Diaqua­bis[5-carb­oxy-2-(3-pyridyl)-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4)]manganese(II)

In the title compound, [Mn(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], synthesized by hydro­thermal reaction, the Mn(II) ion lies on an inversion centre and displays a distorted octa­hedral coordination geometry defined by the two imidazole N atoms and two carboxylate O atoms of the two trans-standing chelate...

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Autor principal: Chen, Li-Zhuang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959396/
https://www.ncbi.nlm.nih.gov/pubmed/21201031
http://dx.doi.org/10.1107/S1600536808029073
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author Chen, Li-Zhuang
author_facet Chen, Li-Zhuang
author_sort Chen, Li-Zhuang
collection PubMed
description In the title compound, [Mn(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], synthesized by hydro­thermal reaction, the Mn(II) ion lies on an inversion centre and displays a distorted octa­hedral coordination geometry defined by the two imidazole N atoms and two carboxylate O atoms of the two trans-standing chelate ligands, and two O atoms of the water mol­ecules. A two-dimensional supra­molecular architecture is formed via N—H⋯O, O—H⋯N and O—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-29593962010-12-30 trans-Diaqua­bis[5-carb­oxy-2-(3-pyridyl)-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4)]manganese(II) Chen, Li-Zhuang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], synthesized by hydro­thermal reaction, the Mn(II) ion lies on an inversion centre and displays a distorted octa­hedral coordination geometry defined by the two imidazole N atoms and two carboxylate O atoms of the two trans-standing chelate ligands, and two O atoms of the water mol­ecules. A two-dimensional supra­molecular architecture is formed via N—H⋯O, O—H⋯N and O—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2008-09-20 /pmc/articles/PMC2959396/ /pubmed/21201031 http://dx.doi.org/10.1107/S1600536808029073 Text en © Li-Zhuang Chen 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Li-Zhuang
trans-Diaqua­bis[5-carb­oxy-2-(3-pyridyl)-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4)]manganese(II)
title trans-Diaqua­bis[5-carb­oxy-2-(3-pyridyl)-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4)]manganese(II)
title_full trans-Diaqua­bis[5-carb­oxy-2-(3-pyridyl)-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4)]manganese(II)
title_fullStr trans-Diaqua­bis[5-carb­oxy-2-(3-pyridyl)-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4)]manganese(II)
title_full_unstemmed trans-Diaqua­bis[5-carb­oxy-2-(3-pyridyl)-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4)]manganese(II)
title_short trans-Diaqua­bis[5-carb­oxy-2-(3-pyridyl)-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4)]manganese(II)
title_sort trans-diaqua­bis[5-carb­oxy-2-(3-pyridyl)-1h-imidazole-4-carboxyl­ato-κ(2) n (3),o (4)]manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959396/
https://www.ncbi.nlm.nih.gov/pubmed/21201031
http://dx.doi.org/10.1107/S1600536808029073
work_keys_str_mv AT chenlizhuang transdiaquabis5carboxy23pyridyl1himidazole4carboxylatok2n3o4manganeseii