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trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ(2) N (3),O (4)]manganese(II)
In the title compound, [Mn(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], synthesized by hydrothermal reaction, the Mn(II) ion lies on an inversion centre and displays a distorted octahedral coordination geometry defined by the two imidazole N atoms and two carboxylate O atoms of the two trans-standing chelate...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959396/ https://www.ncbi.nlm.nih.gov/pubmed/21201031 http://dx.doi.org/10.1107/S1600536808029073 |
| _version_ | 1782188489795698688 |
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| author | Chen, Li-Zhuang |
| author_facet | Chen, Li-Zhuang |
| author_sort | Chen, Li-Zhuang |
| collection | PubMed |
| description | In the title compound, [Mn(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], synthesized by hydrothermal reaction, the Mn(II) ion lies on an inversion centre and displays a distorted octahedral coordination geometry defined by the two imidazole N atoms and two carboxylate O atoms of the two trans-standing chelate ligands, and two O atoms of the water molecules. A two-dimensional supramolecular architecture is formed via N—H⋯O, O—H⋯N and O—H⋯O hydrogen-bonding interactions. |
| format | Text |
| id | pubmed-2959396 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29593962010-12-30 trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ(2) N (3),O (4)]manganese(II) Chen, Li-Zhuang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], synthesized by hydrothermal reaction, the Mn(II) ion lies on an inversion centre and displays a distorted octahedral coordination geometry defined by the two imidazole N atoms and two carboxylate O atoms of the two trans-standing chelate ligands, and two O atoms of the water molecules. A two-dimensional supramolecular architecture is formed via N—H⋯O, O—H⋯N and O—H⋯O hydrogen-bonding interactions. International Union of Crystallography 2008-09-20 /pmc/articles/PMC2959396/ /pubmed/21201031 http://dx.doi.org/10.1107/S1600536808029073 Text en © Li-Zhuang Chen 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Li-Zhuang trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ(2) N (3),O (4)]manganese(II) |
| title |
trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4)]manganese(II) |
| title_full |
trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4)]manganese(II) |
| title_fullStr |
trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4)]manganese(II) |
| title_full_unstemmed |
trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4)]manganese(II) |
| title_short |
trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4)]manganese(II) |
| title_sort | trans-diaquabis[5-carboxy-2-(3-pyridyl)-1h-imidazole-4-carboxylato-κ(2)
n
(3),o
(4)]manganese(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959396/ https://www.ncbi.nlm.nih.gov/pubmed/21201031 http://dx.doi.org/10.1107/S1600536808029073 |
| work_keys_str_mv | AT chenlizhuang transdiaquabis5carboxy23pyridyl1himidazole4carboxylatok2n3o4manganeseii |