2-(Mesitylmethylsulfanyl)pyridine N-oxide monohydrate

In the title compound, C(15)H(17)NOS·H(2)O, the benzene and pyridine rings form a dihedral angle of 71.18 (2)°. The intra­molecular S⋯O distance [2.737 (3) Å] is shorter than expected and, in terms of hybridization principles, the N—C—S angle [114.1 (2)°] is smaller than expected. The crystal struct...

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Detalles Bibliográficos
Autores principales: Ravindran Durai Nayagam, B., Jebas, Samuel Robinson, Johnson Jeyakumar, H., Schollmeyer, Dieter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959397/
https://www.ncbi.nlm.nih.gov/pubmed/21201156
http://dx.doi.org/10.1107/S1600536808029255
Descripción
Sumario:In the title compound, C(15)H(17)NOS·H(2)O, the benzene and pyridine rings form a dihedral angle of 71.18 (2)°. The intra­molecular S⋯O distance [2.737 (3) Å] is shorter than expected and, in terms of hybridization principles, the N—C—S angle [114.1 (2)°] is smaller than expected. The crystal structure is stabilized by inter­molecular O—H⋯O and weak C—H⋯O hydrogen bonds. In addition, weak π–π stacking inter­actions with a centroid–centroid distance of 3.778 (3) Å are also observed.

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