Tricyclo­[6.2.1.0(2,7)]undeca-4,9-diene-3,6-dione

The title compound, C(11)H(10)O(2), crystallizes with two independent mol­ecules in the asymmetric unit. In one mol­ecule, the dihedral angle between the mean planes of the C—C=C—C group of the diene unit and essentially planar cyclo­hexene ring is 51.07 (9)°, while in the other mol­ecule it is 54.4...

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Detalles Bibliográficos
Autor principal: Wang, Chongchen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959398/
https://www.ncbi.nlm.nih.gov/pubmed/21201200
http://dx.doi.org/10.1107/S1600536808030249
Descripción
Sumario:The title compound, C(11)H(10)O(2), crystallizes with two independent mol­ecules in the asymmetric unit. In one mol­ecule, the dihedral angle between the mean planes of the C—C=C—C group of the diene unit and essentially planar cyclo­hexene ring is 51.07 (9)°, while in the other mol­ecule it is 54.49 (12)°. In the crystal structure, weak inter­molecular C—H⋯O inter­actions link the mol­ecules into columns along the b axis.

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