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Butane-1,4-diammonium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cadmate(II) dihydrate
In the title compound, (C(4)H(14)N(2))[Cd(C(7)H(3)NO(4))(2)]·2H(2)O, the Cd(II) ion is coordinated by four O atoms [Cd—O = 2.2399 (17)–2.2493 (17) Å] and two N atoms [Cd—N = 2.3113 (15) and 2.3917 (15) Å] from two tridentate pyridine-2,6-dicarboxylato ligands in a distorted octahedral geometry. Th...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959406/ https://www.ncbi.nlm.nih.gov/pubmed/21201034 http://dx.doi.org/10.1107/S1600536808029395 |
| _version_ | 1782188492118294528 |
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| author | Tabatabaee, Masoumeh Aghabozorg, Hossein Nasrolahzadeh, Roghaieh Roshan, Leila Firoozi, Najmeh |
| author_facet | Tabatabaee, Masoumeh Aghabozorg, Hossein Nasrolahzadeh, Roghaieh Roshan, Leila Firoozi, Najmeh |
| author_sort | Tabatabaee, Masoumeh |
| collection | PubMed |
| description | In the title compound, (C(4)H(14)N(2))[Cd(C(7)H(3)NO(4))(2)]·2H(2)O, the Cd(II) ion is coordinated by four O atoms [Cd—O = 2.2399 (17)–2.2493 (17) Å] and two N atoms [Cd—N = 2.3113 (15) and 2.3917 (15) Å] from two tridentate pyridine-2,6-dicarboxylato ligands in a distorted octahedral geometry. The uncoordinated water molecules are involved in O—H⋯O and N—H⋯O hydrogen bonds, which contribute to the formation of a three-dimensional supramolecular structure, along with π–π stacking interactions [centroid–centroid distances of 3.5313 (13) and 3.6028 (11) Å between the pyridine rings of neighbouring dianions]. |
| format | Text |
| id | pubmed-2959406 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29594062010-12-30 Butane-1,4-diammonium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cadmate(II) dihydrate Tabatabaee, Masoumeh Aghabozorg, Hossein Nasrolahzadeh, Roghaieh Roshan, Leila Firoozi, Najmeh Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(4)H(14)N(2))[Cd(C(7)H(3)NO(4))(2)]·2H(2)O, the Cd(II) ion is coordinated by four O atoms [Cd—O = 2.2399 (17)–2.2493 (17) Å] and two N atoms [Cd—N = 2.3113 (15) and 2.3917 (15) Å] from two tridentate pyridine-2,6-dicarboxylato ligands in a distorted octahedral geometry. The uncoordinated water molecules are involved in O—H⋯O and N—H⋯O hydrogen bonds, which contribute to the formation of a three-dimensional supramolecular structure, along with π–π stacking interactions [centroid–centroid distances of 3.5313 (13) and 3.6028 (11) Å between the pyridine rings of neighbouring dianions]. International Union of Crystallography 2008-09-20 /pmc/articles/PMC2959406/ /pubmed/21201034 http://dx.doi.org/10.1107/S1600536808029395 Text en © Tabatabaee et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Tabatabaee, Masoumeh Aghabozorg, Hossein Nasrolahzadeh, Roghaieh Roshan, Leila Firoozi, Najmeh Butane-1,4-diammonium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cadmate(II) dihydrate |
| title | Butane-1,4-diammonium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cadmate(II) dihydrate |
| title_full | Butane-1,4-diammonium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cadmate(II) dihydrate |
| title_fullStr | Butane-1,4-diammonium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cadmate(II) dihydrate |
| title_full_unstemmed | Butane-1,4-diammonium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cadmate(II) dihydrate |
| title_short | Butane-1,4-diammonium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cadmate(II) dihydrate |
| title_sort | butane-1,4-diammonium bis(pyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))cadmate(ii) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959406/ https://www.ncbi.nlm.nih.gov/pubmed/21201034 http://dx.doi.org/10.1107/S1600536808029395 |
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