fac-Bis(acetonitrile-κN)tricarbonyl­(trifluoro­acetato-κO)rhenium(I)

In the title compound, [Re(CF(3)COO)(CH(3)CN)(2)(CO)(3)], the Re atom has a distorted octa­hedral configuration. The two acetonitrile mol­ecules and two of the three carbonyl groups occupy the equatorial plane of the complex, with the third carbonyl ligand and the trifluoroacetato ligand in the axia...

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Detalles Bibliográficos
Autores principales: Kia, Reza, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959409/
https://www.ncbi.nlm.nih.gov/pubmed/21201050
http://dx.doi.org/10.1107/S1600536808029966
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author Kia, Reza
Fun, Hoong-Kun
author_facet Kia, Reza
Fun, Hoong-Kun
author_sort Kia, Reza
collection PubMed
description In the title compound, [Re(CF(3)COO)(CH(3)CN)(2)(CO)(3)], the Re atom has a distorted octa­hedral configuration. The two acetonitrile mol­ecules and two of the three carbonyl groups occupy the equatorial plane of the complex, with the third carbonyl ligand and the trifluoroacetato ligand in the axial positions. The three carbonyl ligands are arranged in a fac configuration around the Re atom. The CF(3) segment of the trifluoroacetato ligand shows rotational disorder and the refined site-occupancy factors of the disordered parts are ca 0.5/0.5. The crystal structure is stabilized by C—H⋯O and C—H⋯F hydrogen bonds.
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spelling pubmed-29594092010-12-30 fac-Bis(acetonitrile-κN)tricarbonyl­(trifluoro­acetato-κO)rhenium(I) Kia, Reza Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Re(CF(3)COO)(CH(3)CN)(2)(CO)(3)], the Re atom has a distorted octa­hedral configuration. The two acetonitrile mol­ecules and two of the three carbonyl groups occupy the equatorial plane of the complex, with the third carbonyl ligand and the trifluoroacetato ligand in the axial positions. The three carbonyl ligands are arranged in a fac configuration around the Re atom. The CF(3) segment of the trifluoroacetato ligand shows rotational disorder and the refined site-occupancy factors of the disordered parts are ca 0.5/0.5. The crystal structure is stabilized by C—H⋯O and C—H⋯F hydrogen bonds. International Union of Crystallography 2008-09-24 /pmc/articles/PMC2959409/ /pubmed/21201050 http://dx.doi.org/10.1107/S1600536808029966 Text en © Kia and Fun 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kia, Reza
Fun, Hoong-Kun
fac-Bis(acetonitrile-κN)tricarbonyl­(trifluoro­acetato-κO)rhenium(I)
title fac-Bis(acetonitrile-κN)tricarbonyl­(trifluoro­acetato-κO)rhenium(I)
title_full fac-Bis(acetonitrile-κN)tricarbonyl­(trifluoro­acetato-κO)rhenium(I)
title_fullStr fac-Bis(acetonitrile-κN)tricarbonyl­(trifluoro­acetato-κO)rhenium(I)
title_full_unstemmed fac-Bis(acetonitrile-κN)tricarbonyl­(trifluoro­acetato-κO)rhenium(I)
title_short fac-Bis(acetonitrile-κN)tricarbonyl­(trifluoro­acetato-κO)rhenium(I)
title_sort fac-bis(acetonitrile-κn)tricarbonyl­(trifluoro­acetato-κo)rhenium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959409/
https://www.ncbi.nlm.nih.gov/pubmed/21201050
http://dx.doi.org/10.1107/S1600536808029966
work_keys_str_mv AT kiareza facbisacetonitrilekntricarbonyltrifluoroacetatokorheniumi
AT funhoongkun facbisacetonitrilekntricarbonyltrifluoroacetatokorheniumi

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