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catena-Poly[[[diaquamanganese(II)]-μ(3)-pyridine-2,3-dicarboxylato-κ(4) N,O (2):O (3):O (3′)] dihydrate]
In the title coordination polymer, {[Mn(C(7)H(3)NO(4))(H(2)O)(2)]·2H(2)O}(n), the Mn(II) ion is coordinated in a distorted octahedral environment by the O atoms of two water molecules, one N and one O atoms of the chelating pyridine-2,3-dicarboxylate (PDC) dianion, and two axial bridging carboxyl...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959413/ https://www.ncbi.nlm.nih.gov/pubmed/21201037 http://dx.doi.org/10.1107/S1600536808029413 |
Sumario: | In the title coordination polymer, {[Mn(C(7)H(3)NO(4))(H(2)O)(2)]·2H(2)O}(n), the Mn(II) ion is coordinated in a distorted octahedral environment by the O atoms of two water molecules, one N and one O atoms of the chelating pyridine-2,3-dicarboxylate (PDC) dianion, and two axial bridging carboxylate O atoms from two adjacent PDC ligands. The fully deprotonated PDC anion acts a μ(3)-bridging ligand, establishing a chain structure along the a axis. These polymeric chains are connected into a three-dimensional framework via several intermolecular O—H⋯O hydrogen bonds. |
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