catena-Poly[[[diaqua­manganese(II)]-μ(3)-pyridine-2,3-dicarboxyl­ato-κ(4) N,O (2):O (3):O (3′)] dihydrate]

In the title coordination polymer, {[Mn(C(7)H(3)NO(4))(H(2)O)(2)]·2H(2)O}(n), the Mn(II) ion is coordinated in a distorted octahedral environment by the O atoms of two water mol­ecules, one N and one O atoms of the chelating pyridine-2,3-dicarboxyl­ate (PDC) dianion, and two axial bridging carboxyl­...

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Detalles Bibliográficos
Autores principales: Du, Zhong-Xiang, Li, Jun-Xia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959413/
https://www.ncbi.nlm.nih.gov/pubmed/21201037
http://dx.doi.org/10.1107/S1600536808029413
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author Du, Zhong-Xiang
Li, Jun-Xia
author_facet Du, Zhong-Xiang
Li, Jun-Xia
author_sort Du, Zhong-Xiang
collection PubMed
description In the title coordination polymer, {[Mn(C(7)H(3)NO(4))(H(2)O)(2)]·2H(2)O}(n), the Mn(II) ion is coordinated in a distorted octahedral environment by the O atoms of two water mol­ecules, one N and one O atoms of the chelating pyridine-2,3-dicarboxyl­ate (PDC) dianion, and two axial bridging carboxyl­ate O atoms from two adjacent PDC ligands. The fully deprotonated PDC anion acts a μ(3)-bridging ligand, establishing a chain structure along the a axis. These polymeric chains are connected into a three-dimensional framework via several inter­molecular O—H⋯O hydrogen bonds.
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spelling pubmed-29594132010-12-30 catena-Poly[[[diaqua­manganese(II)]-μ(3)-pyridine-2,3-dicarboxyl­ato-κ(4) N,O (2):O (3):O (3′)] dihydrate] Du, Zhong-Xiang Li, Jun-Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Mn(C(7)H(3)NO(4))(H(2)O)(2)]·2H(2)O}(n), the Mn(II) ion is coordinated in a distorted octahedral environment by the O atoms of two water mol­ecules, one N and one O atoms of the chelating pyridine-2,3-dicarboxyl­ate (PDC) dianion, and two axial bridging carboxyl­ate O atoms from two adjacent PDC ligands. The fully deprotonated PDC anion acts a μ(3)-bridging ligand, establishing a chain structure along the a axis. These polymeric chains are connected into a three-dimensional framework via several inter­molecular O—H⋯O hydrogen bonds. International Union of Crystallography 2008-09-20 /pmc/articles/PMC2959413/ /pubmed/21201037 http://dx.doi.org/10.1107/S1600536808029413 Text en © Du and Li 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Du, Zhong-Xiang
Li, Jun-Xia
catena-Poly[[[diaqua­manganese(II)]-μ(3)-pyridine-2,3-dicarboxyl­ato-κ(4) N,O (2):O (3):O (3′)] dihydrate]
title catena-Poly[[[diaqua­manganese(II)]-μ(3)-pyridine-2,3-dicarboxyl­ato-κ(4) N,O (2):O (3):O (3′)] dihydrate]
title_full catena-Poly[[[diaqua­manganese(II)]-μ(3)-pyridine-2,3-dicarboxyl­ato-κ(4) N,O (2):O (3):O (3′)] dihydrate]
title_fullStr catena-Poly[[[diaqua­manganese(II)]-μ(3)-pyridine-2,3-dicarboxyl­ato-κ(4) N,O (2):O (3):O (3′)] dihydrate]
title_full_unstemmed catena-Poly[[[diaqua­manganese(II)]-μ(3)-pyridine-2,3-dicarboxyl­ato-κ(4) N,O (2):O (3):O (3′)] dihydrate]
title_short catena-Poly[[[diaqua­manganese(II)]-μ(3)-pyridine-2,3-dicarboxyl­ato-κ(4) N,O (2):O (3):O (3′)] dihydrate]
title_sort catena-poly[[[diaqua­manganese(ii)]-μ(3)-pyridine-2,3-dicarboxyl­ato-κ(4) n,o (2):o (3):o (3′)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959413/
https://www.ncbi.nlm.nih.gov/pubmed/21201037
http://dx.doi.org/10.1107/S1600536808029413
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