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Diaqua(2,2′-bipyridine-5,5′-dicarboxylato-κ(2) N,N′)(ethylenediamine-κ(2) N,N′)copper(II) 2.5-hydrate
In the molecule of the title compound, [Cu(C(12)H(6)N(2)O(4))(C(2)H(8)N(2))(H(2)O)(2)]·2.5H(2)O, the Cu(II) atom is six-coordinated in a distorted octahedral configuration by two N atoms from a 2,2′-bipyridine-5,5′-dicarboxylate anion, two N atoms from ethylenediamine and two O atoms from two wa...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959425/ https://www.ncbi.nlm.nih.gov/pubmed/21201030 http://dx.doi.org/10.1107/S1600536808029061 |
Sumario: | In the molecule of the title compound, [Cu(C(12)H(6)N(2)O(4))(C(2)H(8)N(2))(H(2)O)(2)]·2.5H(2)O, the Cu(II) atom is six-coordinated in a distorted octahedral configuration by two N atoms from a 2,2′-bipyridine-5,5′-dicarboxylate anion, two N atoms from ethylenediamine and two O atoms from two water molecules. There are also two and a half water molecules in the asymmetric unit. The planar five-membered ring is nearly coplanar with the adjacent pyridine rings, while the other five-membered ring adopts a twisted conformation, probably due to hydrogen bonding. In the crystal structure, intra- and intermolecular N—H⋯O and O—H⋯O hydrogen bonds link the molecules. |
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