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Diaqua(2,2′-bipyridine-5,5′-dicarboxylato-κ(2) N,N′)(ethylenediamine-κ(2) N,N′)copper(II) 2.5-hydrate
In the molecule of the title compound, [Cu(C(12)H(6)N(2)O(4))(C(2)H(8)N(2))(H(2)O)(2)]·2.5H(2)O, the Cu(II) atom is six-coordinated in a distorted octahedral configuration by two N atoms from a 2,2′-bipyridine-5,5′-dicarboxylate anion, two N atoms from ethylenediamine and two O atoms from two wa...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959425/ https://www.ncbi.nlm.nih.gov/pubmed/21201030 http://dx.doi.org/10.1107/S1600536808029061 |
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author | Yousefi, Mohammad Khalighi, Aida Tadayon Pour, Nasim Amani, Vahid Khavasi, Hamid Reza |
author_facet | Yousefi, Mohammad Khalighi, Aida Tadayon Pour, Nasim Amani, Vahid Khavasi, Hamid Reza |
author_sort | Yousefi, Mohammad |
collection | PubMed |
description | In the molecule of the title compound, [Cu(C(12)H(6)N(2)O(4))(C(2)H(8)N(2))(H(2)O)(2)]·2.5H(2)O, the Cu(II) atom is six-coordinated in a distorted octahedral configuration by two N atoms from a 2,2′-bipyridine-5,5′-dicarboxylate anion, two N atoms from ethylenediamine and two O atoms from two water molecules. There are also two and a half water molecules in the asymmetric unit. The planar five-membered ring is nearly coplanar with the adjacent pyridine rings, while the other five-membered ring adopts a twisted conformation, probably due to hydrogen bonding. In the crystal structure, intra- and intermolecular N—H⋯O and O—H⋯O hydrogen bonds link the molecules. |
format | Text |
id | pubmed-2959425 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29594252010-12-30 Diaqua(2,2′-bipyridine-5,5′-dicarboxylato-κ(2) N,N′)(ethylenediamine-κ(2) N,N′)copper(II) 2.5-hydrate Yousefi, Mohammad Khalighi, Aida Tadayon Pour, Nasim Amani, Vahid Khavasi, Hamid Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the molecule of the title compound, [Cu(C(12)H(6)N(2)O(4))(C(2)H(8)N(2))(H(2)O)(2)]·2.5H(2)O, the Cu(II) atom is six-coordinated in a distorted octahedral configuration by two N atoms from a 2,2′-bipyridine-5,5′-dicarboxylate anion, two N atoms from ethylenediamine and two O atoms from two water molecules. There are also two and a half water molecules in the asymmetric unit. The planar five-membered ring is nearly coplanar with the adjacent pyridine rings, while the other five-membered ring adopts a twisted conformation, probably due to hydrogen bonding. In the crystal structure, intra- and intermolecular N—H⋯O and O—H⋯O hydrogen bonds link the molecules. International Union of Crystallography 2008-09-20 /pmc/articles/PMC2959425/ /pubmed/21201030 http://dx.doi.org/10.1107/S1600536808029061 Text en © Yousefi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yousefi, Mohammad Khalighi, Aida Tadayon Pour, Nasim Amani, Vahid Khavasi, Hamid Reza Diaqua(2,2′-bipyridine-5,5′-dicarboxylato-κ(2) N,N′)(ethylenediamine-κ(2) N,N′)copper(II) 2.5-hydrate |
title | Diaqua(2,2′-bipyridine-5,5′-dicarboxylato-κ(2)
N,N′)(ethylenediamine-κ(2)
N,N′)copper(II) 2.5-hydrate |
title_full | Diaqua(2,2′-bipyridine-5,5′-dicarboxylato-κ(2)
N,N′)(ethylenediamine-κ(2)
N,N′)copper(II) 2.5-hydrate |
title_fullStr | Diaqua(2,2′-bipyridine-5,5′-dicarboxylato-κ(2)
N,N′)(ethylenediamine-κ(2)
N,N′)copper(II) 2.5-hydrate |
title_full_unstemmed | Diaqua(2,2′-bipyridine-5,5′-dicarboxylato-κ(2)
N,N′)(ethylenediamine-κ(2)
N,N′)copper(II) 2.5-hydrate |
title_short | Diaqua(2,2′-bipyridine-5,5′-dicarboxylato-κ(2)
N,N′)(ethylenediamine-κ(2)
N,N′)copper(II) 2.5-hydrate |
title_sort | diaqua(2,2′-bipyridine-5,5′-dicarboxylato-κ(2)
n,n′)(ethylenediamine-κ(2)
n,n′)copper(ii) 2.5-hydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959425/ https://www.ncbi.nlm.nih.gov/pubmed/21201030 http://dx.doi.org/10.1107/S1600536808029061 |
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