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Diaqua­(2,2′-bipyridine-5,5′-dicarboxyl­ato-κ(2) N,N′)(ethyl­enediamine-κ(2) N,N′)copper(II) 2.5-hydrate

In the mol­ecule of the title compound, [Cu(C(12)H(6)N(2)O(4))(C(2)H(8)N(2))(H(2)O)(2)]·2.5H(2)O, the Cu(II) atom is six-coordinated in a distorted octa­hedral configuration by two N atoms from a 2,2′-bipyridine-5,5′-dicarboxyl­ate anion, two N atoms from ethyl­enediamine and two O atoms from two wa...

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Detalles Bibliográficos
Autores principales: Yousefi, Mohammad, Khalighi, Aida, Tadayon Pour, Nasim, Amani, Vahid, Khavasi, Hamid Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959425/
https://www.ncbi.nlm.nih.gov/pubmed/21201030
http://dx.doi.org/10.1107/S1600536808029061
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author Yousefi, Mohammad
Khalighi, Aida
Tadayon Pour, Nasim
Amani, Vahid
Khavasi, Hamid Reza
author_facet Yousefi, Mohammad
Khalighi, Aida
Tadayon Pour, Nasim
Amani, Vahid
Khavasi, Hamid Reza
author_sort Yousefi, Mohammad
collection PubMed
description In the mol­ecule of the title compound, [Cu(C(12)H(6)N(2)O(4))(C(2)H(8)N(2))(H(2)O)(2)]·2.5H(2)O, the Cu(II) atom is six-coordinated in a distorted octa­hedral configuration by two N atoms from a 2,2′-bipyridine-5,5′-dicarboxyl­ate anion, two N atoms from ethyl­enediamine and two O atoms from two water mol­ecules. There are also two and a half water mol­ecules in the asymmetric unit. The planar five-membered ring is nearly coplanar with the adjacent pyridine rings, while the other five-membered ring adopts a twisted conformation, probably due to hydrogen bonding. In the crystal structure, intra- and inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link the mol­ecules.
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spelling pubmed-29594252010-12-30 Diaqua­(2,2′-bipyridine-5,5′-dicarboxyl­ato-κ(2) N,N′)(ethyl­enediamine-κ(2) N,N′)copper(II) 2.5-hydrate Yousefi, Mohammad Khalighi, Aida Tadayon Pour, Nasim Amani, Vahid Khavasi, Hamid Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mol­ecule of the title compound, [Cu(C(12)H(6)N(2)O(4))(C(2)H(8)N(2))(H(2)O)(2)]·2.5H(2)O, the Cu(II) atom is six-coordinated in a distorted octa­hedral configuration by two N atoms from a 2,2′-bipyridine-5,5′-dicarboxyl­ate anion, two N atoms from ethyl­enediamine and two O atoms from two water mol­ecules. There are also two and a half water mol­ecules in the asymmetric unit. The planar five-membered ring is nearly coplanar with the adjacent pyridine rings, while the other five-membered ring adopts a twisted conformation, probably due to hydrogen bonding. In the crystal structure, intra- and inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link the mol­ecules. International Union of Crystallography 2008-09-20 /pmc/articles/PMC2959425/ /pubmed/21201030 http://dx.doi.org/10.1107/S1600536808029061 Text en © Yousefi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yousefi, Mohammad
Khalighi, Aida
Tadayon Pour, Nasim
Amani, Vahid
Khavasi, Hamid Reza
Diaqua­(2,2′-bipyridine-5,5′-dicarboxyl­ato-κ(2) N,N′)(ethyl­enediamine-κ(2) N,N′)copper(II) 2.5-hydrate
title Diaqua­(2,2′-bipyridine-5,5′-dicarboxyl­ato-κ(2) N,N′)(ethyl­enediamine-κ(2) N,N′)copper(II) 2.5-hydrate
title_full Diaqua­(2,2′-bipyridine-5,5′-dicarboxyl­ato-κ(2) N,N′)(ethyl­enediamine-κ(2) N,N′)copper(II) 2.5-hydrate
title_fullStr Diaqua­(2,2′-bipyridine-5,5′-dicarboxyl­ato-κ(2) N,N′)(ethyl­enediamine-κ(2) N,N′)copper(II) 2.5-hydrate
title_full_unstemmed Diaqua­(2,2′-bipyridine-5,5′-dicarboxyl­ato-κ(2) N,N′)(ethyl­enediamine-κ(2) N,N′)copper(II) 2.5-hydrate
title_short Diaqua­(2,2′-bipyridine-5,5′-dicarboxyl­ato-κ(2) N,N′)(ethyl­enediamine-κ(2) N,N′)copper(II) 2.5-hydrate
title_sort diaqua­(2,2′-bipyridine-5,5′-dicarboxyl­ato-κ(2) n,n′)(ethyl­enediamine-κ(2) n,n′)copper(ii) 2.5-hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959425/
https://www.ncbi.nlm.nih.gov/pubmed/21201030
http://dx.doi.org/10.1107/S1600536808029061
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