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cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvate
In the title complex, [CoCl(2)(C(12)H(8)N(2))(2)]·C(3)H(7)NO, which has twofold rotation symmetry, the Co(II) cation is coordinated by two 1,10-phenanthroline (phen) molecules and two chloride ligands in a distorted octahedral geometry. In the crystal structure, a cavity is created by six complex...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959430/ https://www.ncbi.nlm.nih.gov/pubmed/21201063 http://dx.doi.org/10.1107/S1600536808030341 |
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author | Cai, Shuang-Lian Ying, Shao-Ming Li, Hui Chen, Yun |
author_facet | Cai, Shuang-Lian Ying, Shao-Ming Li, Hui Chen, Yun |
author_sort | Cai, Shuang-Lian |
collection | PubMed |
description | In the title complex, [CoCl(2)(C(12)H(8)N(2))(2)]·C(3)H(7)NO, which has twofold rotation symmetry, the Co(II) cation is coordinated by two 1,10-phenanthroline (phen) molecules and two chloride ligands in a distorted octahedral geometry. In the crystal structure, a cavity is created by six complex molecules connected by C—H⋯π interactions and non-classical C—H⋯Cl hydrogen bonds. The cavities are occupied by the disordered dimethylformamide solvent molecule. The C and N atoms of the C—N bond in the solvent molecule also lie on a crystallographic twofold rotation axis; the remaining atoms of the solvent are statistically disordered (ratio 0.5:0.5) about this axis. |
format | Text |
id | pubmed-2959430 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29594302010-12-30 cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvate Cai, Shuang-Lian Ying, Shao-Ming Li, Hui Chen, Yun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CoCl(2)(C(12)H(8)N(2))(2)]·C(3)H(7)NO, which has twofold rotation symmetry, the Co(II) cation is coordinated by two 1,10-phenanthroline (phen) molecules and two chloride ligands in a distorted octahedral geometry. In the crystal structure, a cavity is created by six complex molecules connected by C—H⋯π interactions and non-classical C—H⋯Cl hydrogen bonds. The cavities are occupied by the disordered dimethylformamide solvent molecule. The C and N atoms of the C—N bond in the solvent molecule also lie on a crystallographic twofold rotation axis; the remaining atoms of the solvent are statistically disordered (ratio 0.5:0.5) about this axis. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959430/ /pubmed/21201063 http://dx.doi.org/10.1107/S1600536808030341 Text en © Cai et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Cai, Shuang-Lian Ying, Shao-Ming Li, Hui Chen, Yun cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvate |
title |
cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvate |
title_full |
cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvate |
title_fullStr |
cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvate |
title_full_unstemmed |
cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvate |
title_short |
cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethylformamide solvate |
title_sort | cis-dichloridobis(1,10-phenanthroline)cobalt(ii) dimethylformamide solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959430/ https://www.ncbi.nlm.nih.gov/pubmed/21201063 http://dx.doi.org/10.1107/S1600536808030341 |
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