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cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethyl­formamide solvate

In the title complex, [CoCl(2)(C(12)H(8)N(2))(2)]·C(3)H(7)NO, which has twofold rotation symmetry, the Co(II) cation is coordinated by two 1,10-phenanthroline (phen) mol­ecules and two chloride ligands in a distorted octa­hedral geometry. In the crystal structure, a cavity is created by six complex...

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Detalles Bibliográficos
Autores principales: Cai, Shuang-Lian, Ying, Shao-Ming, Li, Hui, Chen, Yun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959430/
https://www.ncbi.nlm.nih.gov/pubmed/21201063
http://dx.doi.org/10.1107/S1600536808030341
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author Cai, Shuang-Lian
Ying, Shao-Ming
Li, Hui
Chen, Yun
author_facet Cai, Shuang-Lian
Ying, Shao-Ming
Li, Hui
Chen, Yun
author_sort Cai, Shuang-Lian
collection PubMed
description In the title complex, [CoCl(2)(C(12)H(8)N(2))(2)]·C(3)H(7)NO, which has twofold rotation symmetry, the Co(II) cation is coordinated by two 1,10-phenanthroline (phen) mol­ecules and two chloride ligands in a distorted octa­hedral geometry. In the crystal structure, a cavity is created by six complex mol­ecules connected by C—H⋯π inter­actions and non-classical C—H⋯Cl hydrogen bonds. The cavities are occupied by the disordered dimethyl­formamide solvent mol­ecule. The C and N atoms of the C—N bond in the solvent mol­ecule also lie on a crystallographic twofold rotation axis; the remaining atoms of the solvent are statistically disordered (ratio 0.5:0.5) about this axis.
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spelling pubmed-29594302010-12-30 cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethyl­formamide solvate Cai, Shuang-Lian Ying, Shao-Ming Li, Hui Chen, Yun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CoCl(2)(C(12)H(8)N(2))(2)]·C(3)H(7)NO, which has twofold rotation symmetry, the Co(II) cation is coordinated by two 1,10-phenanthroline (phen) mol­ecules and two chloride ligands in a distorted octa­hedral geometry. In the crystal structure, a cavity is created by six complex mol­ecules connected by C—H⋯π inter­actions and non-classical C—H⋯Cl hydrogen bonds. The cavities are occupied by the disordered dimethyl­formamide solvent mol­ecule. The C and N atoms of the C—N bond in the solvent mol­ecule also lie on a crystallographic twofold rotation axis; the remaining atoms of the solvent are statistically disordered (ratio 0.5:0.5) about this axis. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959430/ /pubmed/21201063 http://dx.doi.org/10.1107/S1600536808030341 Text en © Cai et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cai, Shuang-Lian
Ying, Shao-Ming
Li, Hui
Chen, Yun
cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethyl­formamide solvate
title cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethyl­formamide solvate
title_full cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethyl­formamide solvate
title_fullStr cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethyl­formamide solvate
title_full_unstemmed cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethyl­formamide solvate
title_short cis-Dichloridobis(1,10-phenanthroline)cobalt(II) dimethyl­formamide solvate
title_sort cis-dichloridobis(1,10-phenanthroline)cobalt(ii) dimethyl­formamide solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959430/
https://www.ncbi.nlm.nih.gov/pubmed/21201063
http://dx.doi.org/10.1107/S1600536808030341
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