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catena-Poly[[aqua­(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2) N (4),N (5))iron(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) N (1),O (2):O (3)]

In the title compound, [Fe(C(6)H(2)N(2)O(4))(C(18)H(10)N(4))(H(2)O)](n), the Fe(II) ion adopts a slightly distorted octahedral mer-FeN(3)O(3) geometry, arising from one N,N′-bidentate dipyrido[3,2-a:2′,3′-c]phenazine ligand, one N,O-chelating pyrazine-2,3-dicarboxyl­ate dianion and one water mol­ecu...

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Detalles Bibliográficos
Autores principales: Xu, Zhan-Lin, Li, Xiu-Ying, Che, Guang-Bo, Lu, Lu, Xu, Chun-Hui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959433/
https://www.ncbi.nlm.nih.gov/pubmed/21201001
http://dx.doi.org/10.1107/S1600536808027153
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author Xu, Zhan-Lin
Li, Xiu-Ying
Che, Guang-Bo
Lu, Lu
Xu, Chun-Hui
author_facet Xu, Zhan-Lin
Li, Xiu-Ying
Che, Guang-Bo
Lu, Lu
Xu, Chun-Hui
author_sort Xu, Zhan-Lin
collection PubMed
description In the title compound, [Fe(C(6)H(2)N(2)O(4))(C(18)H(10)N(4))(H(2)O)](n), the Fe(II) ion adopts a slightly distorted octahedral mer-FeN(3)O(3) geometry, arising from one N,N′-bidentate dipyrido[3,2-a:2′,3′-c]phenazine ligand, one N,O-chelating pyrazine-2,3-dicarboxyl­ate dianion and one water mol­ecule. An O-bonded symmetry-related dianion completes the coordination of the metal. The bridging dianion results in a one-dimensional polymeric chain. Aromatic π–π stacking inter­actions between ligands [centroid–centroid separations = 3.528 (2) and 3.741 (2) Å] and O—H⋯O and O—H⋯N hydrogen bonds link the chains together, leading to a three-dimensional supra­molecular network.
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spelling pubmed-29594332010-12-30 catena-Poly[[aqua­(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2) N (4),N (5))iron(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) N (1),O (2):O (3)] Xu, Zhan-Lin Li, Xiu-Ying Che, Guang-Bo Lu, Lu Xu, Chun-Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(6)H(2)N(2)O(4))(C(18)H(10)N(4))(H(2)O)](n), the Fe(II) ion adopts a slightly distorted octahedral mer-FeN(3)O(3) geometry, arising from one N,N′-bidentate dipyrido[3,2-a:2′,3′-c]phenazine ligand, one N,O-chelating pyrazine-2,3-dicarboxyl­ate dianion and one water mol­ecule. An O-bonded symmetry-related dianion completes the coordination of the metal. The bridging dianion results in a one-dimensional polymeric chain. Aromatic π–π stacking inter­actions between ligands [centroid–centroid separations = 3.528 (2) and 3.741 (2) Å] and O—H⋯O and O—H⋯N hydrogen bonds link the chains together, leading to a three-dimensional supra­molecular network. International Union of Crystallography 2008-09-06 /pmc/articles/PMC2959433/ /pubmed/21201001 http://dx.doi.org/10.1107/S1600536808027153 Text en © Xu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Zhan-Lin
Li, Xiu-Ying
Che, Guang-Bo
Lu, Lu
Xu, Chun-Hui
catena-Poly[[aqua­(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2) N (4),N (5))iron(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) N (1),O (2):O (3)]
title catena-Poly[[aqua­(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2) N (4),N (5))iron(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) N (1),O (2):O (3)]
title_full catena-Poly[[aqua­(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2) N (4),N (5))iron(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) N (1),O (2):O (3)]
title_fullStr catena-Poly[[aqua­(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2) N (4),N (5))iron(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) N (1),O (2):O (3)]
title_full_unstemmed catena-Poly[[aqua­(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2) N (4),N (5))iron(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) N (1),O (2):O (3)]
title_short catena-Poly[[aqua­(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2) N (4),N (5))iron(II)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) N (1),O (2):O (3)]
title_sort catena-poly[[aqua­(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2) n (4),n (5))iron(ii)]-μ-pyrazine-2,3-dicarboxyl­ato-κ(3) n (1),o (2):o (3)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959433/
https://www.ncbi.nlm.nih.gov/pubmed/21201001
http://dx.doi.org/10.1107/S1600536808027153
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