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catena-Poly[[aqua(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2) N (4),N (5))iron(II)]-μ-pyrazine-2,3-dicarboxylato-κ(3) N (1),O (2):O (3)]
In the title compound, [Fe(C(6)H(2)N(2)O(4))(C(18)H(10)N(4))(H(2)O)](n), the Fe(II) ion adopts a slightly distorted octahedral mer-FeN(3)O(3) geometry, arising from one N,N′-bidentate dipyrido[3,2-a:2′,3′-c]phenazine ligand, one N,O-chelating pyrazine-2,3-dicarboxylate dianion and one water molecu...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959433/ https://www.ncbi.nlm.nih.gov/pubmed/21201001 http://dx.doi.org/10.1107/S1600536808027153 |
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author | Xu, Zhan-Lin Li, Xiu-Ying Che, Guang-Bo Lu, Lu Xu, Chun-Hui |
author_facet | Xu, Zhan-Lin Li, Xiu-Ying Che, Guang-Bo Lu, Lu Xu, Chun-Hui |
author_sort | Xu, Zhan-Lin |
collection | PubMed |
description | In the title compound, [Fe(C(6)H(2)N(2)O(4))(C(18)H(10)N(4))(H(2)O)](n), the Fe(II) ion adopts a slightly distorted octahedral mer-FeN(3)O(3) geometry, arising from one N,N′-bidentate dipyrido[3,2-a:2′,3′-c]phenazine ligand, one N,O-chelating pyrazine-2,3-dicarboxylate dianion and one water molecule. An O-bonded symmetry-related dianion completes the coordination of the metal. The bridging dianion results in a one-dimensional polymeric chain. Aromatic π–π stacking interactions between ligands [centroid–centroid separations = 3.528 (2) and 3.741 (2) Å] and O—H⋯O and O—H⋯N hydrogen bonds link the chains together, leading to a three-dimensional supramolecular network. |
format | Text |
id | pubmed-2959433 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29594332010-12-30 catena-Poly[[aqua(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2) N (4),N (5))iron(II)]-μ-pyrazine-2,3-dicarboxylato-κ(3) N (1),O (2):O (3)] Xu, Zhan-Lin Li, Xiu-Ying Che, Guang-Bo Lu, Lu Xu, Chun-Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(6)H(2)N(2)O(4))(C(18)H(10)N(4))(H(2)O)](n), the Fe(II) ion adopts a slightly distorted octahedral mer-FeN(3)O(3) geometry, arising from one N,N′-bidentate dipyrido[3,2-a:2′,3′-c]phenazine ligand, one N,O-chelating pyrazine-2,3-dicarboxylate dianion and one water molecule. An O-bonded symmetry-related dianion completes the coordination of the metal. The bridging dianion results in a one-dimensional polymeric chain. Aromatic π–π stacking interactions between ligands [centroid–centroid separations = 3.528 (2) and 3.741 (2) Å] and O—H⋯O and O—H⋯N hydrogen bonds link the chains together, leading to a three-dimensional supramolecular network. International Union of Crystallography 2008-09-06 /pmc/articles/PMC2959433/ /pubmed/21201001 http://dx.doi.org/10.1107/S1600536808027153 Text en © Xu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xu, Zhan-Lin Li, Xiu-Ying Che, Guang-Bo Lu, Lu Xu, Chun-Hui catena-Poly[[aqua(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2) N (4),N (5))iron(II)]-μ-pyrazine-2,3-dicarboxylato-κ(3) N (1),O (2):O (3)] |
title |
catena-Poly[[aqua(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2)
N
(4),N
(5))iron(II)]-μ-pyrazine-2,3-dicarboxylato-κ(3)
N
(1),O
(2):O
(3)] |
title_full |
catena-Poly[[aqua(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2)
N
(4),N
(5))iron(II)]-μ-pyrazine-2,3-dicarboxylato-κ(3)
N
(1),O
(2):O
(3)] |
title_fullStr |
catena-Poly[[aqua(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2)
N
(4),N
(5))iron(II)]-μ-pyrazine-2,3-dicarboxylato-κ(3)
N
(1),O
(2):O
(3)] |
title_full_unstemmed |
catena-Poly[[aqua(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2)
N
(4),N
(5))iron(II)]-μ-pyrazine-2,3-dicarboxylato-κ(3)
N
(1),O
(2):O
(3)] |
title_short |
catena-Poly[[aqua(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2)
N
(4),N
(5))iron(II)]-μ-pyrazine-2,3-dicarboxylato-κ(3)
N
(1),O
(2):O
(3)] |
title_sort | catena-poly[[aqua(dipyrido[3,2-a:2′,3′-c]phenazine-κ(2)
n
(4),n
(5))iron(ii)]-μ-pyrazine-2,3-dicarboxylato-κ(3)
n
(1),o
(2):o
(3)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959433/ https://www.ncbi.nlm.nih.gov/pubmed/21201001 http://dx.doi.org/10.1107/S1600536808027153 |
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