catena-Poly[[bis­[2-chloro-6-(1H-1,2,4-triazol-1-yl-κN (4))pyridine]cadmium(II)]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]: a one-dimensional coordination polymer

In the crystal structure of the title complex, [Cd(NCS)(2)(C(7)H(5)ClN(4))(2)](n), the Cd(II) atom lies on a crystallographic inversion center and assumes a distorted octa­hedral geometry. The 2-chloro-6-(1H-1,2,4-triazol-1-yl)pyridine mol­ecule acts as a terminal ligand. The thio­cyanate ligands fu...

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Detalles Bibliográficos
Autores principales: Yang, Zhong Nian, Sun, Ting Ting
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959435/
https://www.ncbi.nlm.nih.gov/pubmed/21201062
http://dx.doi.org/10.1107/S1600536808030547
Descripción
Sumario:In the crystal structure of the title complex, [Cd(NCS)(2)(C(7)H(5)ClN(4))(2)](n), the Cd(II) atom lies on a crystallographic inversion center and assumes a distorted octa­hedral geometry. The 2-chloro-6-(1H-1,2,4-triazol-1-yl)pyridine mol­ecule acts as a terminal ligand. The thio­cyanate ligands function as μ(1,3)-bridging units connecting adjacent Cd(II) atoms with a separation of 5.7525 (11) Å, forming a one-dimensional chain along the a axis.

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