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catena-Poly[[bis[2-chloro-6-(1H-1,2,4-triazol-1-yl-κN (4))pyridine]cadmium(II)]-di-μ-thiocyanato-κ(2) N:S;κ(2) S:N]: a one-dimensional coordination polymer
In the crystal structure of the title complex, [Cd(NCS)(2)(C(7)H(5)ClN(4))(2)](n), the Cd(II) atom lies on a crystallographic inversion center and assumes a distorted octahedral geometry. The 2-chloro-6-(1H-1,2,4-triazol-1-yl)pyridine molecule acts as a terminal ligand. The thiocyanate ligands fu...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959435/ https://www.ncbi.nlm.nih.gov/pubmed/21201062 http://dx.doi.org/10.1107/S1600536808030547 |
| _version_ | 1782188499075596288 |
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| author | Yang, Zhong Nian Sun, Ting Ting |
| author_facet | Yang, Zhong Nian Sun, Ting Ting |
| author_sort | Yang, Zhong Nian |
| collection | PubMed |
| description | In the crystal structure of the title complex, [Cd(NCS)(2)(C(7)H(5)ClN(4))(2)](n), the Cd(II) atom lies on a crystallographic inversion center and assumes a distorted octahedral geometry. The 2-chloro-6-(1H-1,2,4-triazol-1-yl)pyridine molecule acts as a terminal ligand. The thiocyanate ligands function as μ(1,3)-bridging units connecting adjacent Cd(II) atoms with a separation of 5.7525 (11) Å, forming a one-dimensional chain along the a axis. |
| format | Text |
| id | pubmed-2959435 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29594352010-12-30 catena-Poly[[bis[2-chloro-6-(1H-1,2,4-triazol-1-yl-κN (4))pyridine]cadmium(II)]-di-μ-thiocyanato-κ(2) N:S;κ(2) S:N]: a one-dimensional coordination polymer Yang, Zhong Nian Sun, Ting Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title complex, [Cd(NCS)(2)(C(7)H(5)ClN(4))(2)](n), the Cd(II) atom lies on a crystallographic inversion center and assumes a distorted octahedral geometry. The 2-chloro-6-(1H-1,2,4-triazol-1-yl)pyridine molecule acts as a terminal ligand. The thiocyanate ligands function as μ(1,3)-bridging units connecting adjacent Cd(II) atoms with a separation of 5.7525 (11) Å, forming a one-dimensional chain along the a axis. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959435/ /pubmed/21201062 http://dx.doi.org/10.1107/S1600536808030547 Text en © Yang and Sun 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Yang, Zhong Nian Sun, Ting Ting catena-Poly[[bis[2-chloro-6-(1H-1,2,4-triazol-1-yl-κN (4))pyridine]cadmium(II)]-di-μ-thiocyanato-κ(2) N:S;κ(2) S:N]: a one-dimensional coordination polymer |
| title |
catena-Poly[[bis[2-chloro-6-(1H-1,2,4-triazol-1-yl-κN
(4))pyridine]cadmium(II)]-di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N]: a one-dimensional coordination polymer |
| title_full |
catena-Poly[[bis[2-chloro-6-(1H-1,2,4-triazol-1-yl-κN
(4))pyridine]cadmium(II)]-di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N]: a one-dimensional coordination polymer |
| title_fullStr |
catena-Poly[[bis[2-chloro-6-(1H-1,2,4-triazol-1-yl-κN
(4))pyridine]cadmium(II)]-di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N]: a one-dimensional coordination polymer |
| title_full_unstemmed |
catena-Poly[[bis[2-chloro-6-(1H-1,2,4-triazol-1-yl-κN
(4))pyridine]cadmium(II)]-di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N]: a one-dimensional coordination polymer |
| title_short |
catena-Poly[[bis[2-chloro-6-(1H-1,2,4-triazol-1-yl-κN
(4))pyridine]cadmium(II)]-di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N]: a one-dimensional coordination polymer |
| title_sort | catena-poly[[bis[2-chloro-6-(1h-1,2,4-triazol-1-yl-κn
(4))pyridine]cadmium(ii)]-di-μ-thiocyanato-κ(2)
n:s;κ(2)
s:n]: a one-dimensional coordination polymer |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959435/ https://www.ncbi.nlm.nih.gov/pubmed/21201062 http://dx.doi.org/10.1107/S1600536808030547 |
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