Cargando…
Bis{2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}thiocyanatozinc(II) nitrate
The title complex, [Zn(NCS)(C(13)H(20)N(2)O(2))(2)]NO(3), consists of a complex mononuclear Zn(II) cation and a nitrate counter-anion. The Zn(II) ion is five-coordinate in a trigonal-bipyramidal geometry. The thiocyanate N atom and two O atoms from two Schiff bases define the equatorial plane, and...
Autor principal: | |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959439/ https://www.ncbi.nlm.nih.gov/pubmed/21201033 http://dx.doi.org/10.1107/S1600536808029590 |
_version_ | 1782188500029800448 |
---|---|
author | Guo, Hui-Rui |
author_facet | Guo, Hui-Rui |
author_sort | Guo, Hui-Rui |
collection | PubMed |
description | The title complex, [Zn(NCS)(C(13)H(20)N(2)O(2))(2)]NO(3), consists of a complex mononuclear Zn(II) cation and a nitrate counter-anion. The Zn(II) ion is five-coordinate in a trigonal-bipyramidal geometry. The thiocyanate N atom and two O atoms from two Schiff bases define the equatorial plane, and the two imine N atoms from the same two Schiff bases occupy the axial positions, with an N—Zn—N angle of 175.98 (7)°. The amine N atoms of the Schiff base ligands are protonated and are not involved in the coordination to the metal. The dihedral angle between the two substituted benzene rings is 87.7 (2)°. The nitrate counter-ions are linked to the cations through N—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2959439 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29594392010-12-30 Bis{2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}thiocyanatozinc(II) nitrate Guo, Hui-Rui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Zn(NCS)(C(13)H(20)N(2)O(2))(2)]NO(3), consists of a complex mononuclear Zn(II) cation and a nitrate counter-anion. The Zn(II) ion is five-coordinate in a trigonal-bipyramidal geometry. The thiocyanate N atom and two O atoms from two Schiff bases define the equatorial plane, and the two imine N atoms from the same two Schiff bases occupy the axial positions, with an N—Zn—N angle of 175.98 (7)°. The amine N atoms of the Schiff base ligands are protonated and are not involved in the coordination to the metal. The dihedral angle between the two substituted benzene rings is 87.7 (2)°. The nitrate counter-ions are linked to the cations through N—H⋯O hydrogen bonds. International Union of Crystallography 2008-09-20 /pmc/articles/PMC2959439/ /pubmed/21201033 http://dx.doi.org/10.1107/S1600536808029590 Text en © Hui-Rui Guo 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Guo, Hui-Rui Bis{2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}thiocyanatozinc(II) nitrate |
title | Bis{2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}thiocyanatozinc(II) nitrate |
title_full | Bis{2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}thiocyanatozinc(II) nitrate |
title_fullStr | Bis{2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}thiocyanatozinc(II) nitrate |
title_full_unstemmed | Bis{2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}thiocyanatozinc(II) nitrate |
title_short | Bis{2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}thiocyanatozinc(II) nitrate |
title_sort | bis{2-ethoxy-6-[2-(ethylammonio)ethyliminomethyl]phenolato}thiocyanatozinc(ii) nitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959439/ https://www.ncbi.nlm.nih.gov/pubmed/21201033 http://dx.doi.org/10.1107/S1600536808029590 |
work_keys_str_mv | AT guohuirui bis2ethoxy62ethylammonioethyliminomethylphenolatothiocyanatozinciinitrate |