N-(1,10-Phenanthrolin-5-yl)-4-(2-pyridyl)­benzamide monohydrate

In the title mol­ecule, C(24)H(16)N(4)O·H(2)O, the benzene ring of the 1,10-phenanthroline group and that of the 2-phenyl­pyridine group are respectively twisted by 67.9 (1) and 15.3 (3)° from the carbamoyl group defined by the plane of the O=C—N group of atoms. The water mol­ecule is hydrogen bonde...

Descripción completa

Detalles Bibliográficos
Autores principales: Kobayashi, Masayuki, Masaoka, Shigeyuki, Sakai, Ken
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959443/
https://www.ncbi.nlm.nih.gov/pubmed/21201179
http://dx.doi.org/10.1107/S1600536808029851
_version_ 1782188501108785152
author Kobayashi, Masayuki
Masaoka, Shigeyuki
Sakai, Ken
author_facet Kobayashi, Masayuki
Masaoka, Shigeyuki
Sakai, Ken
author_sort Kobayashi, Masayuki
collection PubMed
description In the title mol­ecule, C(24)H(16)N(4)O·H(2)O, the benzene ring of the 1,10-phenanthroline group and that of the 2-phenyl­pyridine group are respectively twisted by 67.9 (1) and 15.3 (3)° from the carbamoyl group defined by the plane of the O=C—N group of atoms. The water mol­ecule is hydrogen bonded to one of the phenanthroline N atoms. In the crystal structure, significant π–π stacking inter­actions occur, with centroid-to-centroid separations in the range 3.567–3.681 (2) Å.
format Text
id pubmed-2959443
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29594432010-12-30 N-(1,10-Phenanthrolin-5-yl)-4-(2-pyridyl)­benzamide monohydrate Kobayashi, Masayuki Masaoka, Shigeyuki Sakai, Ken Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(24)H(16)N(4)O·H(2)O, the benzene ring of the 1,10-phenanthroline group and that of the 2-phenyl­pyridine group are respectively twisted by 67.9 (1) and 15.3 (3)° from the carbamoyl group defined by the plane of the O=C—N group of atoms. The water mol­ecule is hydrogen bonded to one of the phenanthroline N atoms. In the crystal structure, significant π–π stacking inter­actions occur, with centroid-to-centroid separations in the range 3.567–3.681 (2) Å. International Union of Crystallography 2008-09-20 /pmc/articles/PMC2959443/ /pubmed/21201179 http://dx.doi.org/10.1107/S1600536808029851 Text en © Kobayashi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kobayashi, Masayuki
Masaoka, Shigeyuki
Sakai, Ken
N-(1,10-Phenanthrolin-5-yl)-4-(2-pyridyl)­benzamide monohydrate
title N-(1,10-Phenanthrolin-5-yl)-4-(2-pyridyl)­benzamide monohydrate
title_full N-(1,10-Phenanthrolin-5-yl)-4-(2-pyridyl)­benzamide monohydrate
title_fullStr N-(1,10-Phenanthrolin-5-yl)-4-(2-pyridyl)­benzamide monohydrate
title_full_unstemmed N-(1,10-Phenanthrolin-5-yl)-4-(2-pyridyl)­benzamide monohydrate
title_short N-(1,10-Phenanthrolin-5-yl)-4-(2-pyridyl)­benzamide monohydrate
title_sort n-(1,10-phenanthrolin-5-yl)-4-(2-pyridyl)­benzamide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959443/
https://www.ncbi.nlm.nih.gov/pubmed/21201179
http://dx.doi.org/10.1107/S1600536808029851
work_keys_str_mv AT kobayashimasayuki n110phenanthrolin5yl42pyridylbenzamidemonohydrate
AT masaokashigeyuki n110phenanthrolin5yl42pyridylbenzamidemonohydrate
AT sakaiken n110phenanthrolin5yl42pyridylbenzamidemonohydrate

Ejemplares similares