catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ(2) N,N′)cadmium(II)]-di-μ-chlorido]

The asymmetric unit of the title compound, [CdCl(2)(C(12)H(12)N(2))](n), contains one half-mol­ecule; a twofold rotation axis passes through the Cd atom. The Cd(II) atom is six-coordinated in a distorted octa­hedral configuration by two N atoms from 2,2′-bipyridine-5,5′-dimethyl and four bridging Cl...

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Autores principales: Ahmadi, Roya, Khalighi, Aida, Kalateh, Khadijeh, Amani, Vahid, Khavasi, Hamid Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959444/
https://www.ncbi.nlm.nih.gov/pubmed/21200993
http://dx.doi.org/10.1107/S1600536808027657
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author Ahmadi, Roya
Khalighi, Aida
Kalateh, Khadijeh
Amani, Vahid
Khavasi, Hamid Reza
author_facet Ahmadi, Roya
Khalighi, Aida
Kalateh, Khadijeh
Amani, Vahid
Khavasi, Hamid Reza
author_sort Ahmadi, Roya
collection PubMed
description The asymmetric unit of the title compound, [CdCl(2)(C(12)H(12)N(2))](n), contains one half-mol­ecule; a twofold rotation axis passes through the Cd atom. The Cd(II) atom is six-coordinated in a distorted octa­hedral configuration by two N atoms from 2,2′-bipyridine-5,5′-dimethyl and four bridging Cl atoms. The bridging function of the chloro atoms leads to a one-dimensional chain structure. There is a π–π contact between the pyridine rings [centroid–centroid distance = 3.9807 (9) Å].
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spelling pubmed-29594442010-12-30 catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ(2) N,N′)cadmium(II)]-di-μ-chlorido] Ahmadi, Roya Khalighi, Aida Kalateh, Khadijeh Amani, Vahid Khavasi, Hamid Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [CdCl(2)(C(12)H(12)N(2))](n), contains one half-mol­ecule; a twofold rotation axis passes through the Cd atom. The Cd(II) atom is six-coordinated in a distorted octa­hedral configuration by two N atoms from 2,2′-bipyridine-5,5′-dimethyl and four bridging Cl atoms. The bridging function of the chloro atoms leads to a one-dimensional chain structure. There is a π–π contact between the pyridine rings [centroid–centroid distance = 3.9807 (9) Å]. International Union of Crystallography 2008-09-06 /pmc/articles/PMC2959444/ /pubmed/21200993 http://dx.doi.org/10.1107/S1600536808027657 Text en © Ahmadi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ahmadi, Roya
Khalighi, Aida
Kalateh, Khadijeh
Amani, Vahid
Khavasi, Hamid Reza
catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ(2) N,N′)cadmium(II)]-di-μ-chlorido]
title catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ(2) N,N′)cadmium(II)]-di-μ-chlorido]
title_full catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ(2) N,N′)cadmium(II)]-di-μ-chlorido]
title_fullStr catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ(2) N,N′)cadmium(II)]-di-μ-chlorido]
title_full_unstemmed catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ(2) N,N′)cadmium(II)]-di-μ-chlorido]
title_short catena-Poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ(2) N,N′)cadmium(II)]-di-μ-chlorido]
title_sort catena-poly[[(5,5′-dimethyl- 2,2′-bipyridine-κ(2) n,n′)cadmium(ii)]-di-μ-chlorido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959444/
https://www.ncbi.nlm.nih.gov/pubmed/21200993
http://dx.doi.org/10.1107/S1600536808027657
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