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Aqua(picolinato N-oxide-κ(2) O (1),O (2))(pyridine-2,6-dicarboxylato-κ(3) O,N,O′)iron(III) monohydrate
In the title compound, [Fe(C(6)H(4)NO(3))(C(7)H(3)NO(4))(H(2)O)]·H(2)O, the Fe(III) ion is coordinated by two O and one N atoms from a pyridine-2,6-dicarboxylate ligand, by two O atoms from a picolinate N-oxide ligand and by one water O atom in a distorted octahedral geometry [Fe—O = 1.940 (3)–2.0...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959446/ https://www.ncbi.nlm.nih.gov/pubmed/21201074 http://dx.doi.org/10.1107/S1600536808030663 |
Sumario: | In the title compound, [Fe(C(6)H(4)NO(3))(C(7)H(3)NO(4))(H(2)O)]·H(2)O, the Fe(III) ion is coordinated by two O and one N atoms from a pyridine-2,6-dicarboxylate ligand, by two O atoms from a picolinate N-oxide ligand and by one water O atom in a distorted octahedral geometry [Fe—O = 1.940 (3)–2.033 (3) Å and Fe—N = 2.057 (4) Å]. In the crystal structure, the coordinated and solvent water molecules contribute to the formation of O—H⋯O hydrogen bonds, which link the molecules into layers parallel to the ab plane. |
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