Cargando…
Aqua(picolinato N-oxide-κ(2) O (1),O (2))(pyridine-2,6-dicarboxylato-κ(3) O,N,O′)iron(III) monohydrate
In the title compound, [Fe(C(6)H(4)NO(3))(C(7)H(3)NO(4))(H(2)O)]·H(2)O, the Fe(III) ion is coordinated by two O and one N atoms from a pyridine-2,6-dicarboxylate ligand, by two O atoms from a picolinate N-oxide ligand and by one water O atom in a distorted octahedral geometry [Fe—O = 1.940 (3)–2.0...
| Autores principales: | , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959446/ https://www.ncbi.nlm.nih.gov/pubmed/21201074 http://dx.doi.org/10.1107/S1600536808030663 |
| _version_ | 1782188501879488512 |
|---|---|
| author | Han, Dongdong Wang, Dong’e |
| author_facet | Han, Dongdong Wang, Dong’e |
| author_sort | Han, Dongdong |
| collection | PubMed |
| description | In the title compound, [Fe(C(6)H(4)NO(3))(C(7)H(3)NO(4))(H(2)O)]·H(2)O, the Fe(III) ion is coordinated by two O and one N atoms from a pyridine-2,6-dicarboxylate ligand, by two O atoms from a picolinate N-oxide ligand and by one water O atom in a distorted octahedral geometry [Fe—O = 1.940 (3)–2.033 (3) Å and Fe—N = 2.057 (4) Å]. In the crystal structure, the coordinated and solvent water molecules contribute to the formation of O—H⋯O hydrogen bonds, which link the molecules into layers parallel to the ab plane. |
| format | Text |
| id | pubmed-2959446 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29594462010-12-30 Aqua(picolinato N-oxide-κ(2) O (1),O (2))(pyridine-2,6-dicarboxylato-κ(3) O,N,O′)iron(III) monohydrate Han, Dongdong Wang, Dong’e Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(6)H(4)NO(3))(C(7)H(3)NO(4))(H(2)O)]·H(2)O, the Fe(III) ion is coordinated by two O and one N atoms from a pyridine-2,6-dicarboxylate ligand, by two O atoms from a picolinate N-oxide ligand and by one water O atom in a distorted octahedral geometry [Fe—O = 1.940 (3)–2.033 (3) Å and Fe—N = 2.057 (4) Å]. In the crystal structure, the coordinated and solvent water molecules contribute to the formation of O—H⋯O hydrogen bonds, which link the molecules into layers parallel to the ab plane. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959446/ /pubmed/21201074 http://dx.doi.org/10.1107/S1600536808030663 Text en © Han and Wang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Han, Dongdong Wang, Dong’e Aqua(picolinato N-oxide-κ(2) O (1),O (2))(pyridine-2,6-dicarboxylato-κ(3) O,N,O′)iron(III) monohydrate |
| title | Aqua(picolinato N-oxide-κ(2)
O
(1),O
(2))(pyridine-2,6-dicarboxylato-κ(3)
O,N,O′)iron(III) monohydrate |
| title_full | Aqua(picolinato N-oxide-κ(2)
O
(1),O
(2))(pyridine-2,6-dicarboxylato-κ(3)
O,N,O′)iron(III) monohydrate |
| title_fullStr | Aqua(picolinato N-oxide-κ(2)
O
(1),O
(2))(pyridine-2,6-dicarboxylato-κ(3)
O,N,O′)iron(III) monohydrate |
| title_full_unstemmed | Aqua(picolinato N-oxide-κ(2)
O
(1),O
(2))(pyridine-2,6-dicarboxylato-κ(3)
O,N,O′)iron(III) monohydrate |
| title_short | Aqua(picolinato N-oxide-κ(2)
O
(1),O
(2))(pyridine-2,6-dicarboxylato-κ(3)
O,N,O′)iron(III) monohydrate |
| title_sort | aqua(picolinato n-oxide-κ(2)
o
(1),o
(2))(pyridine-2,6-dicarboxylato-κ(3)
o,n,o′)iron(iii) monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959446/ https://www.ncbi.nlm.nih.gov/pubmed/21201074 http://dx.doi.org/10.1107/S1600536808030663 |
| work_keys_str_mv | AT handongdong aquapicolinatonoxidek2o1o2pyridine26dicarboxylatok3onoironiiimonohydrate AT wangdonge aquapicolinatonoxidek2o1o2pyridine26dicarboxylatok3onoironiiimonohydrate |