Mg(4)Sb(2)O(9) of the ilmenite structure type

Single crystals of the title compound, tetra­magnesium dianti­monate(V), were obtained by the slow cooling method with K(2)CO(3). The structure is isotypic with ilmenite, which is constructed by the alternate stacking of layers consisting of metal–oxygen coordination octa­hedra. In each layer, the o...

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Autor principal: Michiue, Yuichi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959450/
https://www.ncbi.nlm.nih.gov/pubmed/21200977
http://dx.doi.org/10.1107/S160053680802789X
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author Michiue, Yuichi
author_facet Michiue, Yuichi
author_sort Michiue, Yuichi
collection PubMed
description Single crystals of the title compound, tetra­magnesium dianti­monate(V), were obtained by the slow cooling method with K(2)CO(3). The structure is isotypic with ilmenite, which is constructed by the alternate stacking of layers consisting of metal–oxygen coordination octa­hedra. In each layer, the octa­hedra are connected by sharing edges so as to make holes. One of the two non-equivalent metal sites is fully occupied by Mg (3 symmetry), while the second metal site (3 symmetry) is disordered and occupied by Mg and Sb with occupation factors of 1/3 and 2/3, respectively.
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spelling pubmed-29594502010-12-30 Mg(4)Sb(2)O(9) of the ilmenite structure type Michiue, Yuichi Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Single crystals of the title compound, tetra­magnesium dianti­monate(V), were obtained by the slow cooling method with K(2)CO(3). The structure is isotypic with ilmenite, which is constructed by the alternate stacking of layers consisting of metal–oxygen coordination octa­hedra. In each layer, the octa­hedra are connected by sharing edges so as to make holes. One of the two non-equivalent metal sites is fully occupied by Mg (3 symmetry), while the second metal site (3 symmetry) is disordered and occupied by Mg and Sb with occupation factors of 1/3 and 2/3, respectively. International Union of Crystallography 2008-09-06 /pmc/articles/PMC2959450/ /pubmed/21200977 http://dx.doi.org/10.1107/S160053680802789X Text en © Yuichi Michiue 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Michiue, Yuichi
Mg(4)Sb(2)O(9) of the ilmenite structure type
title Mg(4)Sb(2)O(9) of the ilmenite structure type
title_full Mg(4)Sb(2)O(9) of the ilmenite structure type
title_fullStr Mg(4)Sb(2)O(9) of the ilmenite structure type
title_full_unstemmed Mg(4)Sb(2)O(9) of the ilmenite structure type
title_short Mg(4)Sb(2)O(9) of the ilmenite structure type
title_sort mg(4)sb(2)o(9) of the ilmenite structure type
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959450/
https://www.ncbi.nlm.nih.gov/pubmed/21200977
http://dx.doi.org/10.1107/S160053680802789X
work_keys_str_mv AT michiueyuichi mg4sb2o9oftheilmenitestructuretype

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