1-Bromo­acetyl-2,6-bis­(4-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one

In the title compound, C(23)H(26)BrNO(4), the piperidinone ring adopts a boat conformation. The dihedral angle between the two benzene rings is 70.9 (1)°. The two meth­oxy groups are close to coplanar with the attached benzene rings [C—C—O—C torsion angles of 6.3 (5) and 16.4 (4)°]. A weak C—H⋯Br in...

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Detalles Bibliográficos
Autores principales: Ramachandran, R., Aridoss, G., Velmurugan, D., Kabilan, S., Jeong, Y. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959452/
https://www.ncbi.nlm.nih.gov/pubmed/21201207
http://dx.doi.org/10.1107/S1600536808030213
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author Ramachandran, R.
Aridoss, G.
Velmurugan, D.
Kabilan, S.
Jeong, Y. T.
author_facet Ramachandran, R.
Aridoss, G.
Velmurugan, D.
Kabilan, S.
Jeong, Y. T.
author_sort Ramachandran, R.
collection PubMed
description In the title compound, C(23)H(26)BrNO(4), the piperidinone ring adopts a boat conformation. The dihedral angle between the two benzene rings is 70.9 (1)°. The two meth­oxy groups are close to coplanar with the attached benzene rings [C—C—O—C torsion angles of 6.3 (5) and 16.4 (4)°]. A weak C—H⋯Br intra­molecular inter­action is observed. In the crystal structure, mol­ecules are linked into a chain along [101] by inter­molecular C—H⋯O hydrogen bonds. A short inter­molecular Br⋯O contact [3.063 (2) Å] is observed.
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spelling pubmed-29594522010-12-30 1-Bromo­acetyl-2,6-bis­(4-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one Ramachandran, R. Aridoss, G. Velmurugan, D. Kabilan, S. Jeong, Y. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(26)BrNO(4), the piperidinone ring adopts a boat conformation. The dihedral angle between the two benzene rings is 70.9 (1)°. The two meth­oxy groups are close to coplanar with the attached benzene rings [C—C—O—C torsion angles of 6.3 (5) and 16.4 (4)°]. A weak C—H⋯Br intra­molecular inter­action is observed. In the crystal structure, mol­ecules are linked into a chain along [101] by inter­molecular C—H⋯O hydrogen bonds. A short inter­molecular Br⋯O contact [3.063 (2) Å] is observed. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959452/ /pubmed/21201207 http://dx.doi.org/10.1107/S1600536808030213 Text en © Ramachandran et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ramachandran, R.
Aridoss, G.
Velmurugan, D.
Kabilan, S.
Jeong, Y. T.
1-Bromo­acetyl-2,6-bis­(4-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one
title 1-Bromo­acetyl-2,6-bis­(4-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one
title_full 1-Bromo­acetyl-2,6-bis­(4-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one
title_fullStr 1-Bromo­acetyl-2,6-bis­(4-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one
title_full_unstemmed 1-Bromo­acetyl-2,6-bis­(4-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one
title_short 1-Bromo­acetyl-2,6-bis­(4-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one
title_sort 1-bromo­acetyl-2,6-bis­(4-methoxy­phen­yl)-3,5-dimethyl­piperidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959452/
https://www.ncbi.nlm.nih.gov/pubmed/21201207
http://dx.doi.org/10.1107/S1600536808030213
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AT velmurugand 1bromoacetyl26bis4methoxyphenyl35dimethylpiperidin4one
AT kabilans 1bromoacetyl26bis4methoxyphenyl35dimethylpiperidin4one
AT jeongyt 1bromoacetyl26bis4methoxyphenyl35dimethylpiperidin4one

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