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(E)-1-(4-Aminophenyl)-3-(2-chlorophenyl)prop-2-en-1-one
The title compound, C(15)H(12)ClNO, a substituted chalcone, adopts an E configuration with respect to the C=C bond of the enone unit. The molecule is not planar, as can be seen from the dihedral angle of 28.9 (2)° between the two rings which are twisted from each other. The enone segment of the mol...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959457/ https://www.ncbi.nlm.nih.gov/pubmed/21201210 http://dx.doi.org/10.1107/S1600536808030456 |
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author | Fun, Hoong-Kun Kia, Reza Patil, P. S. Dharmaprakash, S. M. Razak, Ibrahim Abdul |
author_facet | Fun, Hoong-Kun Kia, Reza Patil, P. S. Dharmaprakash, S. M. Razak, Ibrahim Abdul |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | The title compound, C(15)H(12)ClNO, a substituted chalcone, adopts an E configuration with respect to the C=C bond of the enone unit. The molecule is not planar, as can be seen from the dihedral angle of 28.9 (2)° between the two rings which are twisted from each other. The enone segment of the molecule is not coplanar with the chlorophenyl ring, making a dihedral angle of 23.4 (3)° with it. The amino group is also not coplanar with the ring to which it is bound, making a dihedral angle of 35 (4)°. In the crystal structure, adjacent molecules are linked by N—H⋯O interactions into one-dimensional infinite chains along the c axis, and are further stacked as one-dimensional zigzag chains down the b axis, forming two-dimensional extended networks parallel to the bc plane. |
format | Text |
id | pubmed-2959457 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29594572010-12-30 (E)-1-(4-Aminophenyl)-3-(2-chlorophenyl)prop-2-en-1-one Fun, Hoong-Kun Kia, Reza Patil, P. S. Dharmaprakash, S. M. Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(12)ClNO, a substituted chalcone, adopts an E configuration with respect to the C=C bond of the enone unit. The molecule is not planar, as can be seen from the dihedral angle of 28.9 (2)° between the two rings which are twisted from each other. The enone segment of the molecule is not coplanar with the chlorophenyl ring, making a dihedral angle of 23.4 (3)° with it. The amino group is also not coplanar with the ring to which it is bound, making a dihedral angle of 35 (4)°. In the crystal structure, adjacent molecules are linked by N—H⋯O interactions into one-dimensional infinite chains along the c axis, and are further stacked as one-dimensional zigzag chains down the b axis, forming two-dimensional extended networks parallel to the bc plane. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959457/ /pubmed/21201210 http://dx.doi.org/10.1107/S1600536808030456 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Kia, Reza Patil, P. S. Dharmaprakash, S. M. Razak, Ibrahim Abdul (E)-1-(4-Aminophenyl)-3-(2-chlorophenyl)prop-2-en-1-one |
title | (E)-1-(4-Aminophenyl)-3-(2-chlorophenyl)prop-2-en-1-one |
title_full | (E)-1-(4-Aminophenyl)-3-(2-chlorophenyl)prop-2-en-1-one |
title_fullStr | (E)-1-(4-Aminophenyl)-3-(2-chlorophenyl)prop-2-en-1-one |
title_full_unstemmed | (E)-1-(4-Aminophenyl)-3-(2-chlorophenyl)prop-2-en-1-one |
title_short | (E)-1-(4-Aminophenyl)-3-(2-chlorophenyl)prop-2-en-1-one |
title_sort | (e)-1-(4-aminophenyl)-3-(2-chlorophenyl)prop-2-en-1-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959457/ https://www.ncbi.nlm.nih.gov/pubmed/21201210 http://dx.doi.org/10.1107/S1600536808030456 |
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