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(E)-1-(4-Amino­phen­yl)-3-(2-chloro­phen­yl)prop-2-en-1-one

The title compound, C(15)H(12)ClNO, a substituted chalcone, adopts an E configuration with respect to the C=C bond of the enone unit. The mol­ecule is not planar, as can be seen from the dihedral angle of 28.9 (2)° between the two rings which are twisted from each other. The enone segment of the mol...

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Autores principales: Fun, Hoong-Kun, Kia, Reza, Patil, P. S., Dharmaprakash, S. M., Razak, Ibrahim Abdul
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959457/
https://www.ncbi.nlm.nih.gov/pubmed/21201210
http://dx.doi.org/10.1107/S1600536808030456
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author Fun, Hoong-Kun
Kia, Reza
Patil, P. S.
Dharmaprakash, S. M.
Razak, Ibrahim Abdul
author_facet Fun, Hoong-Kun
Kia, Reza
Patil, P. S.
Dharmaprakash, S. M.
Razak, Ibrahim Abdul
author_sort Fun, Hoong-Kun
collection PubMed
description The title compound, C(15)H(12)ClNO, a substituted chalcone, adopts an E configuration with respect to the C=C bond of the enone unit. The mol­ecule is not planar, as can be seen from the dihedral angle of 28.9 (2)° between the two rings which are twisted from each other. The enone segment of the mol­ecule is not coplanar with the chloro­phenyl ring, making a dihedral angle of 23.4 (3)° with it. The amino group is also not coplanar with the ring to which it is bound, making a dihedral angle of 35 (4)°. In the crystal structure, adjacent mol­ecules are linked by N—H⋯O inter­actions into one-dimensional infinite chains along the c axis, and are further stacked as one-dimensional zigzag chains down the b axis, forming two-dimensional extended networks parallel to the bc plane.
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spelling pubmed-29594572010-12-30 (E)-1-(4-Amino­phen­yl)-3-(2-chloro­phen­yl)prop-2-en-1-one Fun, Hoong-Kun Kia, Reza Patil, P. S. Dharmaprakash, S. M. Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(12)ClNO, a substituted chalcone, adopts an E configuration with respect to the C=C bond of the enone unit. The mol­ecule is not planar, as can be seen from the dihedral angle of 28.9 (2)° between the two rings which are twisted from each other. The enone segment of the mol­ecule is not coplanar with the chloro­phenyl ring, making a dihedral angle of 23.4 (3)° with it. The amino group is also not coplanar with the ring to which it is bound, making a dihedral angle of 35 (4)°. In the crystal structure, adjacent mol­ecules are linked by N—H⋯O inter­actions into one-dimensional infinite chains along the c axis, and are further stacked as one-dimensional zigzag chains down the b axis, forming two-dimensional extended networks parallel to the bc plane. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959457/ /pubmed/21201210 http://dx.doi.org/10.1107/S1600536808030456 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Kia, Reza
Patil, P. S.
Dharmaprakash, S. M.
Razak, Ibrahim Abdul
(E)-1-(4-Amino­phen­yl)-3-(2-chloro­phen­yl)prop-2-en-1-one
title (E)-1-(4-Amino­phen­yl)-3-(2-chloro­phen­yl)prop-2-en-1-one
title_full (E)-1-(4-Amino­phen­yl)-3-(2-chloro­phen­yl)prop-2-en-1-one
title_fullStr (E)-1-(4-Amino­phen­yl)-3-(2-chloro­phen­yl)prop-2-en-1-one
title_full_unstemmed (E)-1-(4-Amino­phen­yl)-3-(2-chloro­phen­yl)prop-2-en-1-one
title_short (E)-1-(4-Amino­phen­yl)-3-(2-chloro­phen­yl)prop-2-en-1-one
title_sort (e)-1-(4-amino­phen­yl)-3-(2-chloro­phen­yl)prop-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959457/
https://www.ncbi.nlm.nih.gov/pubmed/21201210
http://dx.doi.org/10.1107/S1600536808030456
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