Tetrakis(μ-2-chloro­benzoato-κ(2) O:O′)bis­[(4-vinyl­pyridine-κN)copper(II)]

The title compound, [Cu(2)(C(7)H(4)ClO(2))(4)(C(7)H(7)N)(2)], consists of centrosymmetric dinuclear mol­ecules with a Cu⋯Cu separation of 2.6676 (12) Å. In the mol­ecule, four 2-chloro­benzoate anions bridge two Cu(II) ions, while two neutral 4-vinyl­pyridine ligands coordinate them in axial positio...

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Detalles Bibliográficos
Autor principal: Zhao, Juan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959459/
https://www.ncbi.nlm.nih.gov/pubmed/21201069
http://dx.doi.org/10.1107/S1600536808030766
Descripción
Sumario:The title compound, [Cu(2)(C(7)H(4)ClO(2))(4)(C(7)H(7)N)(2)], consists of centrosymmetric dinuclear mol­ecules with a Cu⋯Cu separation of 2.6676 (12) Å. In the mol­ecule, four 2-chloro­benzoate anions bridge two Cu(II) ions, while two neutral 4-vinyl­pyridine ligands coordinate them in axial positions. The Cu(II) ion has a distorted square-planar pyramidal coordination, with four O atoms from the chlorobenzoate anions at the base. The N pyridine atom completes the coordination environment in the apical position.

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