Tetrakis(μ-2-chloro­benzoato-κ(2) O:O′)bis­[(4-vinyl­pyridine-κN)copper(II)]

The title compound, [Cu(2)(C(7)H(4)ClO(2))(4)(C(7)H(7)N)(2)], consists of centrosymmetric dinuclear mol­ecules with a Cu⋯Cu separation of 2.6676 (12) Å. In the mol­ecule, four 2-chloro­benzoate anions bridge two Cu(II) ions, while two neutral 4-vinyl­pyridine ligands coordinate them in axial positio...

Descripción completa

Detalles Bibliográficos
Autor principal: Zhao, Juan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959459/
https://www.ncbi.nlm.nih.gov/pubmed/21201069
http://dx.doi.org/10.1107/S1600536808030766
_version_ 1782188504945524736
author Zhao, Juan
author_facet Zhao, Juan
author_sort Zhao, Juan
collection PubMed
description The title compound, [Cu(2)(C(7)H(4)ClO(2))(4)(C(7)H(7)N)(2)], consists of centrosymmetric dinuclear mol­ecules with a Cu⋯Cu separation of 2.6676 (12) Å. In the mol­ecule, four 2-chloro­benzoate anions bridge two Cu(II) ions, while two neutral 4-vinyl­pyridine ligands coordinate them in axial positions. The Cu(II) ion has a distorted square-planar pyramidal coordination, with four O atoms from the chlorobenzoate anions at the base. The N pyridine atom completes the coordination environment in the apical position.
format Text
id pubmed-2959459
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29594592010-12-30 Tetrakis(μ-2-chloro­benzoato-κ(2) O:O′)bis­[(4-vinyl­pyridine-κN)copper(II)] Zhao, Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(7)H(4)ClO(2))(4)(C(7)H(7)N)(2)], consists of centrosymmetric dinuclear mol­ecules with a Cu⋯Cu separation of 2.6676 (12) Å. In the mol­ecule, four 2-chloro­benzoate anions bridge two Cu(II) ions, while two neutral 4-vinyl­pyridine ligands coordinate them in axial positions. The Cu(II) ion has a distorted square-planar pyramidal coordination, with four O atoms from the chlorobenzoate anions at the base. The N pyridine atom completes the coordination environment in the apical position. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959459/ /pubmed/21201069 http://dx.doi.org/10.1107/S1600536808030766 Text en © Juan Zhao 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Juan
Tetrakis(μ-2-chloro­benzoato-κ(2) O:O′)bis­[(4-vinyl­pyridine-κN)copper(II)]
title Tetrakis(μ-2-chloro­benzoato-κ(2) O:O′)bis­[(4-vinyl­pyridine-κN)copper(II)]
title_full Tetrakis(μ-2-chloro­benzoato-κ(2) O:O′)bis­[(4-vinyl­pyridine-κN)copper(II)]
title_fullStr Tetrakis(μ-2-chloro­benzoato-κ(2) O:O′)bis­[(4-vinyl­pyridine-κN)copper(II)]
title_full_unstemmed Tetrakis(μ-2-chloro­benzoato-κ(2) O:O′)bis­[(4-vinyl­pyridine-κN)copper(II)]
title_short Tetrakis(μ-2-chloro­benzoato-κ(2) O:O′)bis­[(4-vinyl­pyridine-κN)copper(II)]
title_sort tetrakis(μ-2-chloro­benzoato-κ(2) o:o′)bis­[(4-vinyl­pyridine-κn)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959459/
https://www.ncbi.nlm.nih.gov/pubmed/21201069
http://dx.doi.org/10.1107/S1600536808030766
work_keys_str_mv AT zhaojuan tetrakism2chlorobenzoatok2oobis4vinylpyridinekncopperii

Ejemplares similares