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catena-Poly[[dipyridinemercury(II)]-μ-5-amino-2,4,6-triiodoisophthalato]
The reaction of mercury(II) chloride with 5-amino-2,4,6-triiodoisophthalic acid in pyridine solution leads to the formation of the title compound, [Hg(C(8)H(2)I(3)NO(4))(C(5)H(5)N)(2)](n). The structure contains a four-coordinate Hg(2+) ion in a distorted tetrahedral geometry, which lies on a crys...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959462/ https://www.ncbi.nlm.nih.gov/pubmed/21201059 http://dx.doi.org/10.1107/S1600536808030468 |
Sumario: | The reaction of mercury(II) chloride with 5-amino-2,4,6-triiodoisophthalic acid in pyridine solution leads to the formation of the title compound, [Hg(C(8)H(2)I(3)NO(4))(C(5)H(5)N)(2)](n). The structure contains a four-coordinate Hg(2+) ion in a distorted tetrahedral geometry, which lies on a crystallographic twofold axis. The Hg(2+) ion is bonded to two N atoms from two pyridine ligands and two carboxylate O atoms from two 5-amino-2,4,6-triiodoisophthalate anions. The two carboxylate groups of individual 5-amino-2,4,6-triiodoisophthalate anions act as a bridge to the Hg centers. This anion also resides on a twofold axis, which passes through the amino N and the trans standing I atoms. The Hg—O distance is 2.337 (6) and the Hg—N distance is 2.244 (8) Å. |
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