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catena-Poly[[dipyridine­mercury(II)]-μ-5-amino-2,4,6-triiodo­isophthalato]

The reaction of mercury(II) chloride with 5-amino-2,4,6-triiodo­isophthalic acid in pyridine solution leads to the formation of the title compound, [Hg(C(8)H(2)I(3)NO(4))(C(5)H(5)N)(2)](n). The structure contains a four-coordinate Hg(2+) ion in a distorted tetra­hedral geometry, which lies on a crys...

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Detalles Bibliográficos
Autores principales: Zhang, Yu, Zhao, Jianying, Tang, Guodong, Jiang, Zhengjing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959462/
https://www.ncbi.nlm.nih.gov/pubmed/21201059
http://dx.doi.org/10.1107/S1600536808030468
Descripción
Sumario:The reaction of mercury(II) chloride with 5-amino-2,4,6-triiodo­isophthalic acid in pyridine solution leads to the formation of the title compound, [Hg(C(8)H(2)I(3)NO(4))(C(5)H(5)N)(2)](n). The structure contains a four-coordinate Hg(2+) ion in a distorted tetra­hedral geometry, which lies on a crystallographic twofold axis. The Hg(2+) ion is bonded to two N atoms from two pyridine ligands and two carboxylate O atoms from two 5-amino-2,4,6-triiodo­isophthalate anions. The two carboxyl­ate groups of individual 5-amino-2,4,6-triiodo­isophthalate anions act as a bridge to the Hg centers. This anion also resides on a twofold axis, which passes through the amino N and the trans standing I atoms. The Hg—O distance is 2.337 (6) and the Hg—N distance is 2.244 (8) Å.