Cargando…

catena-Poly[[dipyridine­mercury(II)]-μ-5-amino-2,4,6-triiodo­isophthalato]

The reaction of mercury(II) chloride with 5-amino-2,4,6-triiodo­isophthalic acid in pyridine solution leads to the formation of the title compound, [Hg(C(8)H(2)I(3)NO(4))(C(5)H(5)N)(2)](n). The structure contains a four-coordinate Hg(2+) ion in a distorted tetra­hedral geometry, which lies on a crys...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Yu, Zhao, Jianying, Tang, Guodong, Jiang, Zhengjing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959462/
https://www.ncbi.nlm.nih.gov/pubmed/21201059
http://dx.doi.org/10.1107/S1600536808030468
_version_ 1782188505664847872
author Zhang, Yu
Zhao, Jianying
Tang, Guodong
Jiang, Zhengjing
author_facet Zhang, Yu
Zhao, Jianying
Tang, Guodong
Jiang, Zhengjing
author_sort Zhang, Yu
collection PubMed
description The reaction of mercury(II) chloride with 5-amino-2,4,6-triiodo­isophthalic acid in pyridine solution leads to the formation of the title compound, [Hg(C(8)H(2)I(3)NO(4))(C(5)H(5)N)(2)](n). The structure contains a four-coordinate Hg(2+) ion in a distorted tetra­hedral geometry, which lies on a crystallographic twofold axis. The Hg(2+) ion is bonded to two N atoms from two pyridine ligands and two carboxylate O atoms from two 5-amino-2,4,6-triiodo­isophthalate anions. The two carboxyl­ate groups of individual 5-amino-2,4,6-triiodo­isophthalate anions act as a bridge to the Hg centers. This anion also resides on a twofold axis, which passes through the amino N and the trans standing I atoms. The Hg—O distance is 2.337 (6) and the Hg—N distance is 2.244 (8) Å.
format Text
id pubmed-2959462
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29594622010-12-30 catena-Poly[[dipyridine­mercury(II)]-μ-5-amino-2,4,6-triiodo­isophthalato] Zhang, Yu Zhao, Jianying Tang, Guodong Jiang, Zhengjing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of mercury(II) chloride with 5-amino-2,4,6-triiodo­isophthalic acid in pyridine solution leads to the formation of the title compound, [Hg(C(8)H(2)I(3)NO(4))(C(5)H(5)N)(2)](n). The structure contains a four-coordinate Hg(2+) ion in a distorted tetra­hedral geometry, which lies on a crystallographic twofold axis. The Hg(2+) ion is bonded to two N atoms from two pyridine ligands and two carboxylate O atoms from two 5-amino-2,4,6-triiodo­isophthalate anions. The two carboxyl­ate groups of individual 5-amino-2,4,6-triiodo­isophthalate anions act as a bridge to the Hg centers. This anion also resides on a twofold axis, which passes through the amino N and the trans standing I atoms. The Hg—O distance is 2.337 (6) and the Hg—N distance is 2.244 (8) Å. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959462/ /pubmed/21201059 http://dx.doi.org/10.1107/S1600536808030468 Text en © Yu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Yu
Zhao, Jianying
Tang, Guodong
Jiang, Zhengjing
catena-Poly[[dipyridine­mercury(II)]-μ-5-amino-2,4,6-triiodo­isophthalato]
title catena-Poly[[dipyridine­mercury(II)]-μ-5-amino-2,4,6-triiodo­isophthalato]
title_full catena-Poly[[dipyridine­mercury(II)]-μ-5-amino-2,4,6-triiodo­isophthalato]
title_fullStr catena-Poly[[dipyridine­mercury(II)]-μ-5-amino-2,4,6-triiodo­isophthalato]
title_full_unstemmed catena-Poly[[dipyridine­mercury(II)]-μ-5-amino-2,4,6-triiodo­isophthalato]
title_short catena-Poly[[dipyridine­mercury(II)]-μ-5-amino-2,4,6-triiodo­isophthalato]
title_sort catena-poly[[dipyridine­mercury(ii)]-μ-5-amino-2,4,6-triiodo­isophthalato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959462/
https://www.ncbi.nlm.nih.gov/pubmed/21201059
http://dx.doi.org/10.1107/S1600536808030468
work_keys_str_mv AT zhangyu catenapolydipyridinemercuryiim5amino246triiodoisophthalato
AT zhaojianying catenapolydipyridinemercuryiim5amino246triiodoisophthalato
AT tangguodong catenapolydipyridinemercuryiim5amino246triiodoisophthalato
AT jiangzhengjing catenapolydipyridinemercuryiim5amino246triiodoisophthalato