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catena-Poly[[dipyridinemercury(II)]-μ-5-amino-2,4,6-triiodoisophthalato]
The reaction of mercury(II) chloride with 5-amino-2,4,6-triiodoisophthalic acid in pyridine solution leads to the formation of the title compound, [Hg(C(8)H(2)I(3)NO(4))(C(5)H(5)N)(2)](n). The structure contains a four-coordinate Hg(2+) ion in a distorted tetrahedral geometry, which lies on a crys...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959462/ https://www.ncbi.nlm.nih.gov/pubmed/21201059 http://dx.doi.org/10.1107/S1600536808030468 |
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author | Zhang, Yu Zhao, Jianying Tang, Guodong Jiang, Zhengjing |
author_facet | Zhang, Yu Zhao, Jianying Tang, Guodong Jiang, Zhengjing |
author_sort | Zhang, Yu |
collection | PubMed |
description | The reaction of mercury(II) chloride with 5-amino-2,4,6-triiodoisophthalic acid in pyridine solution leads to the formation of the title compound, [Hg(C(8)H(2)I(3)NO(4))(C(5)H(5)N)(2)](n). The structure contains a four-coordinate Hg(2+) ion in a distorted tetrahedral geometry, which lies on a crystallographic twofold axis. The Hg(2+) ion is bonded to two N atoms from two pyridine ligands and two carboxylate O atoms from two 5-amino-2,4,6-triiodoisophthalate anions. The two carboxylate groups of individual 5-amino-2,4,6-triiodoisophthalate anions act as a bridge to the Hg centers. This anion also resides on a twofold axis, which passes through the amino N and the trans standing I atoms. The Hg—O distance is 2.337 (6) and the Hg—N distance is 2.244 (8) Å. |
format | Text |
id | pubmed-2959462 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29594622010-12-30 catena-Poly[[dipyridinemercury(II)]-μ-5-amino-2,4,6-triiodoisophthalato] Zhang, Yu Zhao, Jianying Tang, Guodong Jiang, Zhengjing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of mercury(II) chloride with 5-amino-2,4,6-triiodoisophthalic acid in pyridine solution leads to the formation of the title compound, [Hg(C(8)H(2)I(3)NO(4))(C(5)H(5)N)(2)](n). The structure contains a four-coordinate Hg(2+) ion in a distorted tetrahedral geometry, which lies on a crystallographic twofold axis. The Hg(2+) ion is bonded to two N atoms from two pyridine ligands and two carboxylate O atoms from two 5-amino-2,4,6-triiodoisophthalate anions. The two carboxylate groups of individual 5-amino-2,4,6-triiodoisophthalate anions act as a bridge to the Hg centers. This anion also resides on a twofold axis, which passes through the amino N and the trans standing I atoms. The Hg—O distance is 2.337 (6) and the Hg—N distance is 2.244 (8) Å. International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959462/ /pubmed/21201059 http://dx.doi.org/10.1107/S1600536808030468 Text en © Yu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Yu Zhao, Jianying Tang, Guodong Jiang, Zhengjing catena-Poly[[dipyridinemercury(II)]-μ-5-amino-2,4,6-triiodoisophthalato] |
title |
catena-Poly[[dipyridinemercury(II)]-μ-5-amino-2,4,6-triiodoisophthalato] |
title_full |
catena-Poly[[dipyridinemercury(II)]-μ-5-amino-2,4,6-triiodoisophthalato] |
title_fullStr |
catena-Poly[[dipyridinemercury(II)]-μ-5-amino-2,4,6-triiodoisophthalato] |
title_full_unstemmed |
catena-Poly[[dipyridinemercury(II)]-μ-5-amino-2,4,6-triiodoisophthalato] |
title_short |
catena-Poly[[dipyridinemercury(II)]-μ-5-amino-2,4,6-triiodoisophthalato] |
title_sort | catena-poly[[dipyridinemercury(ii)]-μ-5-amino-2,4,6-triiodoisophthalato] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959462/ https://www.ncbi.nlm.nih.gov/pubmed/21201059 http://dx.doi.org/10.1107/S1600536808030468 |
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