A P,O,P′-tridentate mixed-donor scorpionate ligand: 6-[4,6-bis­(diphenyl­phosphino)-10H-phenoxazin-10-yl]hexan-1-ol

The title compound, C(42)H(39)NO(2)P(2), is a P,O,P′-tridentate scorpionate-type ligand and has one mol­ecule in the asymmetric unit. The angles involving the P atoms range from 100.21 (7) to 104.89 (7)°. The N-hexa­nol group was found to be disordered and was refined over two positions with final o...

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Detalles Bibliográficos
Autores principales: Marimuthu, Thashree, Bala, Muhammad D., Friedrich, Holger B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959466/
https://www.ncbi.nlm.nih.gov/pubmed/21201184
http://dx.doi.org/10.1107/S1600536808030134
Descripción
Sumario:The title compound, C(42)H(39)NO(2)P(2), is a P,O,P′-tridentate scorpionate-type ligand and has one mol­ecule in the asymmetric unit. The angles involving the P atoms range from 100.21 (7) to 104.89 (7)°. The N-hexa­nol group was found to be disordered and was refined over two positions with final occupancies of 0.683 (3) and 0.317 (3) which affected the C—O and C—N bond lengths. The bond lengths for C—O range from 1.402 (2) to 1.415 (2) Å and for C—N from 1.410 (2) to 1.448 (3) Å for the major disorder component; the corresponding ranges for the minor disorder component are 1.429 (3)–1.408 (3) and 1.474 (3)–1.474 (4) Å.

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