r-2,c-6-Bis(4-chloro­phen­yl)-t-3-isopropyl-1-nitro­sopiperidin-4-one

In the title mol­ecule, C(20)H(20)Cl(2)N(2)O(2), the piperidine ring adopts a chair conformation and the nitroso group at position 1 has a bis­ectional orientation. The two benzene rings and the isopropyl group attached to the piperidine ring in positions 2, 6 and 3, respectively, have axial orienta...

Descripción completa

Detalles Bibliográficos
Autores principales: Gayathri, P., Thiruvalluvar, A., Manimekalai, A., Sivakumar, S., Butcher, R. J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959467/
https://www.ncbi.nlm.nih.gov/pubmed/21201173
http://dx.doi.org/10.1107/S1600536808029723
_version_ 1782188506867564544
author Gayathri, P.
Thiruvalluvar, A.
Manimekalai, A.
Sivakumar, S.
Butcher, R. J.
author_facet Gayathri, P.
Thiruvalluvar, A.
Manimekalai, A.
Sivakumar, S.
Butcher, R. J.
author_sort Gayathri, P.
collection PubMed
description In the title mol­ecule, C(20)H(20)Cl(2)N(2)O(2), the piperidine ring adopts a chair conformation and the nitroso group at position 1 has a bis­ectional orientation. The two benzene rings and the isopropyl group attached to the piperidine ring in positions 2, 6 and 3, respectively, have axial orientations. The dihedral angle between the two benzene rings is 21.56 (13)°. One of the Cl atoms is disordered over two positions in a 0.281 (5):0.719 (5) ratio. In the crystal structure, mol­ecules are linked by C—H⋯O hydrogen bonds and a short C—H⋯O contact occurs within the mol­ecule.
format Text
id pubmed-2959467
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29594672010-12-30 r-2,c-6-Bis(4-chloro­phen­yl)-t-3-isopropyl-1-nitro­sopiperidin-4-one Gayathri, P. Thiruvalluvar, A. Manimekalai, A. Sivakumar, S. Butcher, R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(20)H(20)Cl(2)N(2)O(2), the piperidine ring adopts a chair conformation and the nitroso group at position 1 has a bis­ectional orientation. The two benzene rings and the isopropyl group attached to the piperidine ring in positions 2, 6 and 3, respectively, have axial orientations. The dihedral angle between the two benzene rings is 21.56 (13)°. One of the Cl atoms is disordered over two positions in a 0.281 (5):0.719 (5) ratio. In the crystal structure, mol­ecules are linked by C—H⋯O hydrogen bonds and a short C—H⋯O contact occurs within the mol­ecule. International Union of Crystallography 2008-09-20 /pmc/articles/PMC2959467/ /pubmed/21201173 http://dx.doi.org/10.1107/S1600536808029723 Text en © Gayathri et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gayathri, P.
Thiruvalluvar, A.
Manimekalai, A.
Sivakumar, S.
Butcher, R. J.
r-2,c-6-Bis(4-chloro­phen­yl)-t-3-isopropyl-1-nitro­sopiperidin-4-one
title r-2,c-6-Bis(4-chloro­phen­yl)-t-3-isopropyl-1-nitro­sopiperidin-4-one
title_full r-2,c-6-Bis(4-chloro­phen­yl)-t-3-isopropyl-1-nitro­sopiperidin-4-one
title_fullStr r-2,c-6-Bis(4-chloro­phen­yl)-t-3-isopropyl-1-nitro­sopiperidin-4-one
title_full_unstemmed r-2,c-6-Bis(4-chloro­phen­yl)-t-3-isopropyl-1-nitro­sopiperidin-4-one
title_short r-2,c-6-Bis(4-chloro­phen­yl)-t-3-isopropyl-1-nitro­sopiperidin-4-one
title_sort r-2,c-6-bis(4-chloro­phen­yl)-t-3-isopropyl-1-nitro­sopiperidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959467/
https://www.ncbi.nlm.nih.gov/pubmed/21201173
http://dx.doi.org/10.1107/S1600536808029723
work_keys_str_mv AT gayathrip r2c6bis4chlorophenylt3isopropyl1nitrosopiperidin4one
AT thiruvalluvara r2c6bis4chlorophenylt3isopropyl1nitrosopiperidin4one
AT manimekalaia r2c6bis4chlorophenylt3isopropyl1nitrosopiperidin4one
AT sivakumars r2c6bis4chlorophenylt3isopropyl1nitrosopiperidin4one
AT butcherrj r2c6bis4chlorophenylt3isopropyl1nitrosopiperidin4one

Ejemplares similares