Diaqua­(2,5-di-4-pyridyl-1,3,4-thia­diazole-κN (2))bis­(thio­cyanato-κN)nickel(II) dihydrate

In the title mononuclear complex, [Ni(NCS)(2)(C(12)H(8)N(4)S)(2)(H(2)O)(2)]·2H(2)O, the Ni(II) atom is located on an inversion center and is octa­hedrally coordinated by four N atoms from two 2,5-di-4-pyridyl-1,3,4-thia­diazole (bpt) ligands and two thio­cyanate mol­ecules forming the equatorial pla...

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Detalles Bibliográficos
Autor principal: Yang, Ming-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959476/
https://www.ncbi.nlm.nih.gov/pubmed/21201065
http://dx.doi.org/10.1107/S1600536808030444
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author Yang, Ming-Hua
author_facet Yang, Ming-Hua
author_sort Yang, Ming-Hua
collection PubMed
description In the title mononuclear complex, [Ni(NCS)(2)(C(12)H(8)N(4)S)(2)(H(2)O)(2)]·2H(2)O, the Ni(II) atom is located on an inversion center and is octa­hedrally coordinated by four N atoms from two 2,5-di-4-pyridyl-1,3,4-thia­diazole (bpt) ligands and two thio­cyanate mol­ecules forming the equatorial plane; the axial positions are occupied by two O atoms of coordinated water mol­ecules. O—H⋯O, O—H⋯N and O—H⋯S hydrogen bonds, involving the uncoordinated water molecules, result in the formation of a sheet structure developing parallel to (021).
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spelling pubmed-29594762010-12-30 Diaqua­(2,5-di-4-pyridyl-1,3,4-thia­diazole-κN (2))bis­(thio­cyanato-κN)nickel(II) dihydrate Yang, Ming-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Ni(NCS)(2)(C(12)H(8)N(4)S)(2)(H(2)O)(2)]·2H(2)O, the Ni(II) atom is located on an inversion center and is octa­hedrally coordinated by four N atoms from two 2,5-di-4-pyridyl-1,3,4-thia­diazole (bpt) ligands and two thio­cyanate mol­ecules forming the equatorial plane; the axial positions are occupied by two O atoms of coordinated water mol­ecules. O—H⋯O, O—H⋯N and O—H⋯S hydrogen bonds, involving the uncoordinated water molecules, result in the formation of a sheet structure developing parallel to (021). International Union of Crystallography 2008-09-27 /pmc/articles/PMC2959476/ /pubmed/21201065 http://dx.doi.org/10.1107/S1600536808030444 Text en © Ming-Hua Yang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Ming-Hua
Diaqua­(2,5-di-4-pyridyl-1,3,4-thia­diazole-κN (2))bis­(thio­cyanato-κN)nickel(II) dihydrate
title Diaqua­(2,5-di-4-pyridyl-1,3,4-thia­diazole-κN (2))bis­(thio­cyanato-κN)nickel(II) dihydrate
title_full Diaqua­(2,5-di-4-pyridyl-1,3,4-thia­diazole-κN (2))bis­(thio­cyanato-κN)nickel(II) dihydrate
title_fullStr Diaqua­(2,5-di-4-pyridyl-1,3,4-thia­diazole-κN (2))bis­(thio­cyanato-κN)nickel(II) dihydrate
title_full_unstemmed Diaqua­(2,5-di-4-pyridyl-1,3,4-thia­diazole-κN (2))bis­(thio­cyanato-κN)nickel(II) dihydrate
title_short Diaqua­(2,5-di-4-pyridyl-1,3,4-thia­diazole-κN (2))bis­(thio­cyanato-κN)nickel(II) dihydrate
title_sort diaqua­(2,5-di-4-pyridyl-1,3,4-thia­diazole-κn (2))bis­(thio­cyanato-κn)nickel(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959476/
https://www.ncbi.nlm.nih.gov/pubmed/21201065
http://dx.doi.org/10.1107/S1600536808030444
work_keys_str_mv AT yangminghua diaqua25di4pyridyl134thiadiazolekn2bisthiocyanatoknnickeliidihydrate

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