Bis(ethano­lato-κO)(5,10,15,20-tetra­phenyl­calix[4]pyrrole)manganese(III) hexa­fluoro­phosphate

The title compound, [Mn(C(2)H(5)O)(2)(C(44)H(28)N(4))]PF(6), was synthesized from manganese(III) 2,4-penta­nedionate and 5,10,15,20-tetra­phenyl­calix[4]pyrrole by a hydro­thermal reaction. The Mn(III) atom is located on an inversion centre and the asymmetric unit comprises one half-formula unit. The Mn(III) ion is hexa­coordinated by four N atoms from one 5,10,15,20-tetra­phenyl­calix[4]pyrrole ligand and two O atoms from two deprotonated ethanol mol­ecules. The equatorially located atoms (the Mn and four N atoms) are planar. The dihedral angles between the planes of the phenyl rings and the equatorial plane are 53.3 (2) and 81.8 (2)°. One hexa­fluoro­phosphate anion balances the charge.