Bis(ethano­lato-κO)(5,10,15,20-tetra­phenyl­calix[4]pyrrole)manganese(III) hexa­fluoro­phosphate

The title compound, [Mn(C(2)H(5)O)(2)(C(44)H(28)N(4))]PF(6), was synthesized from manganese(III) 2,4-penta­nedionate and 5,10,15,20-tetra­phenyl­calix[4]pyrrole by a hydro­thermal reaction. The Mn(III) atom is located on an inversion centre and the asymmetric unit comprises one half-formula unit. Th...

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Detalles Bibliográficos
Autores principales: Wang, Suwen, Li, Zhongfang, Wang, Xutao, Yu, Xianjin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959478/
https://www.ncbi.nlm.nih.gov/pubmed/21200992
http://dx.doi.org/10.1107/S1600536808021879
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author Wang, Suwen
Li, Zhongfang
Wang, Xutao
Yu, Xianjin
author_facet Wang, Suwen
Li, Zhongfang
Wang, Xutao
Yu, Xianjin
author_sort Wang, Suwen
collection PubMed
description The title compound, [Mn(C(2)H(5)O)(2)(C(44)H(28)N(4))]PF(6), was synthesized from manganese(III) 2,4-penta­nedionate and 5,10,15,20-tetra­phenyl­calix[4]pyrrole by a hydro­thermal reaction. The Mn(III) atom is located on an inversion centre and the asymmetric unit comprises one half-formula unit. The Mn(III) ion is hexa­coordinated by four N atoms from one 5,10,15,20-tetra­phenyl­calix[4]pyrrole ligand and two O atoms from two deprotonated ethanol mol­ecules. The equatorially located atoms (the Mn and four N atoms) are planar. The dihedral angles between the planes of the phenyl rings and the equatorial plane are 53.3 (2) and 81.8 (2)°. One hexa­fluoro­phosphate anion balances the charge.
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spelling pubmed-29594782010-12-30 Bis(ethano­lato-κO)(5,10,15,20-tetra­phenyl­calix[4]pyrrole)manganese(III) hexa­fluoro­phosphate Wang, Suwen Li, Zhongfang Wang, Xutao Yu, Xianjin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(C(2)H(5)O)(2)(C(44)H(28)N(4))]PF(6), was synthesized from manganese(III) 2,4-penta­nedionate and 5,10,15,20-tetra­phenyl­calix[4]pyrrole by a hydro­thermal reaction. The Mn(III) atom is located on an inversion centre and the asymmetric unit comprises one half-formula unit. The Mn(III) ion is hexa­coordinated by four N atoms from one 5,10,15,20-tetra­phenyl­calix[4]pyrrole ligand and two O atoms from two deprotonated ethanol mol­ecules. The equatorially located atoms (the Mn and four N atoms) are planar. The dihedral angles between the planes of the phenyl rings and the equatorial plane are 53.3 (2) and 81.8 (2)°. One hexa­fluoro­phosphate anion balances the charge. International Union of Crystallography 2008-09-06 /pmc/articles/PMC2959478/ /pubmed/21200992 http://dx.doi.org/10.1107/S1600536808021879 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Suwen
Li, Zhongfang
Wang, Xutao
Yu, Xianjin
Bis(ethano­lato-κO)(5,10,15,20-tetra­phenyl­calix[4]pyrrole)manganese(III) hexa­fluoro­phosphate
title Bis(ethano­lato-κO)(5,10,15,20-tetra­phenyl­calix[4]pyrrole)manganese(III) hexa­fluoro­phosphate
title_full Bis(ethano­lato-κO)(5,10,15,20-tetra­phenyl­calix[4]pyrrole)manganese(III) hexa­fluoro­phosphate
title_fullStr Bis(ethano­lato-κO)(5,10,15,20-tetra­phenyl­calix[4]pyrrole)manganese(III) hexa­fluoro­phosphate
title_full_unstemmed Bis(ethano­lato-κO)(5,10,15,20-tetra­phenyl­calix[4]pyrrole)manganese(III) hexa­fluoro­phosphate
title_short Bis(ethano­lato-κO)(5,10,15,20-tetra­phenyl­calix[4]pyrrole)manganese(III) hexa­fluoro­phosphate
title_sort bis(ethano­lato-κo)(5,10,15,20-tetra­phenyl­calix[4]pyrrole)manganese(iii) hexa­fluoro­phosphate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959478/
https://www.ncbi.nlm.nih.gov/pubmed/21200992
http://dx.doi.org/10.1107/S1600536808021879
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AT wangxutao bisethanolatoko5101520tetraphenylcalix4pyrrolemanganeseiiihexafluorophosphate
AT yuxianjin bisethanolatoko5101520tetraphenylcalix4pyrrolemanganeseiiihexafluorophosphate

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