Cargando…
Hexa-μ(2)-acetato-κ(12) O:O′-μ(3)-oxido-tris[aquachromium(III)] nitrate acetic acid solvate
In the crystal structure of the title salt, [Cr(3)(C(2)H(3)O(2))(6)O(H(2)O)(3)]NO(3)·CH(3)CO(2)H, the trinuclear [Cr(3)(CH(3)CO(2))(6)O(H(2)O)(3)] cluster cation has an oxide O atom that is connected to three water-coordinated Cr(III) atoms, the three metal atoms forming the points of an equilateral...
| Autores principales: | , , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959480/ https://www.ncbi.nlm.nih.gov/pubmed/21201047 http://dx.doi.org/10.1107/S1600536808029681 |
| _version_ | 1782188509946183680 |
|---|---|
| author | Maah, Mohd Jamil Abdullah, Che Ibrahim Gan, Seng Neon Mohd Jelan, Aishah Ng, Seik Weng |
| author_facet | Maah, Mohd Jamil Abdullah, Che Ibrahim Gan, Seng Neon Mohd Jelan, Aishah Ng, Seik Weng |
| author_sort | Maah, Mohd Jamil |
| collection | PubMed |
| description | In the crystal structure of the title salt, [Cr(3)(C(2)H(3)O(2))(6)O(H(2)O)(3)]NO(3)·CH(3)CO(2)H, the trinuclear [Cr(3)(CH(3)CO(2))(6)O(H(2)O)(3)] cluster cation has an oxide O atom that is connected to three water-coordinated Cr(III) atoms, the three metal atoms forming the points of an equilateral triangle. Each of the six acetate carboxylate groups bridges a Cr–O–Cr fragment. The cluster cation interacts with the nitrate counter-ion and solvent molecules through O—H⋯O hydrogen bonds, forming a three-dimensional hydrogen-bonded network. |
| format | Text |
| id | pubmed-2959480 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29594802010-12-30 Hexa-μ(2)-acetato-κ(12) O:O′-μ(3)-oxido-tris[aquachromium(III)] nitrate acetic acid solvate Maah, Mohd Jamil Abdullah, Che Ibrahim Gan, Seng Neon Mohd Jelan, Aishah Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title salt, [Cr(3)(C(2)H(3)O(2))(6)O(H(2)O)(3)]NO(3)·CH(3)CO(2)H, the trinuclear [Cr(3)(CH(3)CO(2))(6)O(H(2)O)(3)] cluster cation has an oxide O atom that is connected to three water-coordinated Cr(III) atoms, the three metal atoms forming the points of an equilateral triangle. Each of the six acetate carboxylate groups bridges a Cr–O–Cr fragment. The cluster cation interacts with the nitrate counter-ion and solvent molecules through O—H⋯O hydrogen bonds, forming a three-dimensional hydrogen-bonded network. International Union of Crystallography 2008-09-24 /pmc/articles/PMC2959480/ /pubmed/21201047 http://dx.doi.org/10.1107/S1600536808029681 Text en © Maah et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Maah, Mohd Jamil Abdullah, Che Ibrahim Gan, Seng Neon Mohd Jelan, Aishah Ng, Seik Weng Hexa-μ(2)-acetato-κ(12) O:O′-μ(3)-oxido-tris[aquachromium(III)] nitrate acetic acid solvate |
| title | Hexa-μ(2)-acetato-κ(12)
O:O′-μ(3)-oxido-tris[aquachromium(III)] nitrate acetic acid solvate |
| title_full | Hexa-μ(2)-acetato-κ(12)
O:O′-μ(3)-oxido-tris[aquachromium(III)] nitrate acetic acid solvate |
| title_fullStr | Hexa-μ(2)-acetato-κ(12)
O:O′-μ(3)-oxido-tris[aquachromium(III)] nitrate acetic acid solvate |
| title_full_unstemmed | Hexa-μ(2)-acetato-κ(12)
O:O′-μ(3)-oxido-tris[aquachromium(III)] nitrate acetic acid solvate |
| title_short | Hexa-μ(2)-acetato-κ(12)
O:O′-μ(3)-oxido-tris[aquachromium(III)] nitrate acetic acid solvate |
| title_sort | hexa-μ(2)-acetato-κ(12)
o:o′-μ(3)-oxido-tris[aquachromium(iii)] nitrate acetic acid solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959480/ https://www.ncbi.nlm.nih.gov/pubmed/21201047 http://dx.doi.org/10.1107/S1600536808029681 |
| work_keys_str_mv | AT maahmohdjamil hexam2acetatok12oom3oxidotrisaquachromiumiiinitrateaceticacidsolvate AT abdullahcheibrahim hexam2acetatok12oom3oxidotrisaquachromiumiiinitrateaceticacidsolvate AT gansengneon hexam2acetatok12oom3oxidotrisaquachromiumiiinitrateaceticacidsolvate AT mohdjelanaishah hexam2acetatok12oom3oxidotrisaquachromiumiiinitrateaceticacidsolvate AT ngseikweng hexam2acetatok12oom3oxidotrisaquachromiumiiinitrateaceticacidsolvate |