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Bis(2,6-dimethyl­phenyl isocyanide-κC)gold(I) tetra­fluorido­borate

In the title compound, [Au(C(9)H(9)N)(2)]BF(4), the Au(I) cation adopts an almost linear AuC(2) geometry. The cation is bowed due to crystal packing effects, and the dihedral angle between the xylyl rings is 52.3 (7)°.

Detalles Bibliográficos
Autores principales: Singa, Timi P., DiPasquale, Antonio G., Rheingold, Arnold L., Kubiak, Clifford P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959487/
https://www.ncbi.nlm.nih.gov/pubmed/21200982
http://dx.doi.org/10.1107/S1600536808027116
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author Singa, Timi P.
DiPasquale, Antonio G.
Rheingold, Arnold L.
Kubiak, Clifford P.
author_facet Singa, Timi P.
DiPasquale, Antonio G.
Rheingold, Arnold L.
Kubiak, Clifford P.
author_sort Singa, Timi P.
collection PubMed
description In the title compound, [Au(C(9)H(9)N)(2)]BF(4), the Au(I) cation adopts an almost linear AuC(2) geometry. The cation is bowed due to crystal packing effects, and the dihedral angle between the xylyl rings is 52.3 (7)°.
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spelling pubmed-29594872010-12-30 Bis(2,6-dimethyl­phenyl isocyanide-κC)gold(I) tetra­fluorido­borate Singa, Timi P. DiPasquale, Antonio G. Rheingold, Arnold L. Kubiak, Clifford P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Au(C(9)H(9)N)(2)]BF(4), the Au(I) cation adopts an almost linear AuC(2) geometry. The cation is bowed due to crystal packing effects, and the dihedral angle between the xylyl rings is 52.3 (7)°. International Union of Crystallography 2008-09-06 /pmc/articles/PMC2959487/ /pubmed/21200982 http://dx.doi.org/10.1107/S1600536808027116 Text en © Singa et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Singa, Timi P.
DiPasquale, Antonio G.
Rheingold, Arnold L.
Kubiak, Clifford P.
Bis(2,6-dimethyl­phenyl isocyanide-κC)gold(I) tetra­fluorido­borate
title Bis(2,6-dimethyl­phenyl isocyanide-κC)gold(I) tetra­fluorido­borate
title_full Bis(2,6-dimethyl­phenyl isocyanide-κC)gold(I) tetra­fluorido­borate
title_fullStr Bis(2,6-dimethyl­phenyl isocyanide-κC)gold(I) tetra­fluorido­borate
title_full_unstemmed Bis(2,6-dimethyl­phenyl isocyanide-κC)gold(I) tetra­fluorido­borate
title_short Bis(2,6-dimethyl­phenyl isocyanide-κC)gold(I) tetra­fluorido­borate
title_sort bis(2,6-dimethyl­phenyl isocyanide-κc)gold(i) tetra­fluorido­borate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959487/
https://www.ncbi.nlm.nih.gov/pubmed/21200982
http://dx.doi.org/10.1107/S1600536808027116
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AT kubiakcliffordp bis26dimethylphenylisocyanidekcgolditetrafluoridoborate