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Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborate
In the title compound, [Au(C(9)H(9)N)(2)]BF(4), the Au(I) cation adopts an almost linear AuC(2) geometry. The cation is bowed due to crystal packing effects, and the dihedral angle between the xylyl rings is 52.3 (7)°.
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959487/ https://www.ncbi.nlm.nih.gov/pubmed/21200982 http://dx.doi.org/10.1107/S1600536808027116 |
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author | Singa, Timi P. DiPasquale, Antonio G. Rheingold, Arnold L. Kubiak, Clifford P. |
author_facet | Singa, Timi P. DiPasquale, Antonio G. Rheingold, Arnold L. Kubiak, Clifford P. |
author_sort | Singa, Timi P. |
collection | PubMed |
description | In the title compound, [Au(C(9)H(9)N)(2)]BF(4), the Au(I) cation adopts an almost linear AuC(2) geometry. The cation is bowed due to crystal packing effects, and the dihedral angle between the xylyl rings is 52.3 (7)°. |
format | Text |
id | pubmed-2959487 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29594872010-12-30 Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborate Singa, Timi P. DiPasquale, Antonio G. Rheingold, Arnold L. Kubiak, Clifford P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Au(C(9)H(9)N)(2)]BF(4), the Au(I) cation adopts an almost linear AuC(2) geometry. The cation is bowed due to crystal packing effects, and the dihedral angle between the xylyl rings is 52.3 (7)°. International Union of Crystallography 2008-09-06 /pmc/articles/PMC2959487/ /pubmed/21200982 http://dx.doi.org/10.1107/S1600536808027116 Text en © Singa et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Singa, Timi P. DiPasquale, Antonio G. Rheingold, Arnold L. Kubiak, Clifford P. Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborate |
title | Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborate |
title_full | Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborate |
title_fullStr | Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborate |
title_full_unstemmed | Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborate |
title_short | Bis(2,6-dimethylphenyl isocyanide-κC)gold(I) tetrafluoridoborate |
title_sort | bis(2,6-dimethylphenyl isocyanide-κc)gold(i) tetrafluoridoborate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959487/ https://www.ncbi.nlm.nih.gov/pubmed/21200982 http://dx.doi.org/10.1107/S1600536808027116 |
work_keys_str_mv | AT singatimip bis26dimethylphenylisocyanidekcgolditetrafluoridoborate AT dipasqualeantoniog bis26dimethylphenylisocyanidekcgolditetrafluoridoborate AT rheingoldarnoldl bis26dimethylphenylisocyanidekcgolditetrafluoridoborate AT kubiakcliffordp bis26dimethylphenylisocyanidekcgolditetrafluoridoborate |