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Poly[diaquabis[μ(2)-2,4-(dichlorophenoxy)acetato-κ(2) O:O′]iron(II)]
In the title compound, [Fe(C(8)H(5)Cl(2)O(3))(2)(H(2)O)(2)](n), the Fe(II) atom is located on an inversion center. It is coordinated by four O atoms from four 2,4-dichlorophenoxyacetate ligands and two water molecules, displaying a distorted octahedral geometry. The carboxylate groups of the 2,...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959489/ https://www.ncbi.nlm.nih.gov/pubmed/21201032 http://dx.doi.org/10.1107/S1600536808029279 |
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| author | Pan, Wei-Bo Xu, Xiao-Hong Huang, Xiao-Hui Zeng, Rong-Hua |
| author_facet | Pan, Wei-Bo Xu, Xiao-Hong Huang, Xiao-Hui Zeng, Rong-Hua |
| author_sort | Pan, Wei-Bo |
| collection | PubMed |
| description | In the title compound, [Fe(C(8)H(5)Cl(2)O(3))(2)(H(2)O)(2)](n), the Fe(II) atom is located on an inversion center. It is coordinated by four O atoms from four 2,4-dichlorophenoxyacetate ligands and two water molecules, displaying a distorted octahedral geometry. The carboxylate groups of the 2,4-dichlorophenoxyacetate ligands link the Fe atoms, forming a polymeric layered network in the bc plane. Intralayer O—H⋯O hydrogen bonds enhance the stability of the two-dimensional network. |
| format | Text |
| id | pubmed-2959489 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29594892010-12-30 Poly[diaquabis[μ(2)-2,4-(dichlorophenoxy)acetato-κ(2) O:O′]iron(II)] Pan, Wei-Bo Xu, Xiao-Hong Huang, Xiao-Hui Zeng, Rong-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(8)H(5)Cl(2)O(3))(2)(H(2)O)(2)](n), the Fe(II) atom is located on an inversion center. It is coordinated by four O atoms from four 2,4-dichlorophenoxyacetate ligands and two water molecules, displaying a distorted octahedral geometry. The carboxylate groups of the 2,4-dichlorophenoxyacetate ligands link the Fe atoms, forming a polymeric layered network in the bc plane. Intralayer O—H⋯O hydrogen bonds enhance the stability of the two-dimensional network. International Union of Crystallography 2008-09-20 /pmc/articles/PMC2959489/ /pubmed/21201032 http://dx.doi.org/10.1107/S1600536808029279 Text en © Pan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Pan, Wei-Bo Xu, Xiao-Hong Huang, Xiao-Hui Zeng, Rong-Hua Poly[diaquabis[μ(2)-2,4-(dichlorophenoxy)acetato-κ(2) O:O′]iron(II)] |
| title | Poly[diaquabis[μ(2)-2,4-(dichlorophenoxy)acetato-κ(2)
O:O′]iron(II)] |
| title_full | Poly[diaquabis[μ(2)-2,4-(dichlorophenoxy)acetato-κ(2)
O:O′]iron(II)] |
| title_fullStr | Poly[diaquabis[μ(2)-2,4-(dichlorophenoxy)acetato-κ(2)
O:O′]iron(II)] |
| title_full_unstemmed | Poly[diaquabis[μ(2)-2,4-(dichlorophenoxy)acetato-κ(2)
O:O′]iron(II)] |
| title_short | Poly[diaquabis[μ(2)-2,4-(dichlorophenoxy)acetato-κ(2)
O:O′]iron(II)] |
| title_sort | poly[diaquabis[μ(2)-2,4-(dichlorophenoxy)acetato-κ(2)
o:o′]iron(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959489/ https://www.ncbi.nlm.nih.gov/pubmed/21201032 http://dx.doi.org/10.1107/S1600536808029279 |
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