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1-(4-Nitro­benzo­yl)-3-(4-nitro­phen­yl)­thio­urea acetone hemisolvate

In the title compound, C(14)H(10)N(4)O(5)S·0.5C(3)H(6)O, the nitro­benzoyl and nitro­phenyl groups have trans and cis configurations, respectively, with respect to the thio­urea S atom. The mol­ecular conformation is stabilized by intra­molecular N—H⋯O and C—H⋯S hydrogen bonds. The acetone solvent m...

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Detalles Bibliográficos
Autores principales: Xian, Liang, Cui, Lujuan, Cheng, Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959497/
https://www.ncbi.nlm.nih.gov/pubmed/21580998
http://dx.doi.org/10.1107/S160053680803359X
Descripción
Sumario:In the title compound, C(14)H(10)N(4)O(5)S·0.5C(3)H(6)O, the nitro­benzoyl and nitro­phenyl groups have trans and cis configurations, respectively, with respect to the thio­urea S atom. The mol­ecular conformation is stabilized by intra­molecular N—H⋯O and C—H⋯S hydrogen bonds. The acetone solvent mol­ecule possesses a crystallographically imposed twofold axis. In the crystal packing, thio­urea mol­ecules are linked by inter­molecular C—H⋯O hydrogen-bond inter­actions to form chains running parallel to the c axis. The chains are further bridged via N—H⋯O and C—H⋯O hydrogen bonds involving the acetone mol­ecules.