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A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II)
In the structure of the title compound, [PdCl(2)(C(5)H(5)N)(2)], the Pd(II) atom is located on an inversion centre and the pyridine rings are coplanar. There is intermolecular π–π stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916 (1) Å. The structure is a new polym...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959498/ https://www.ncbi.nlm.nih.gov/pubmed/21580886 http://dx.doi.org/10.1107/S1600536808033552 |
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author | Lee, Hon Man Liao, Chuang-Yi |
author_facet | Lee, Hon Man Liao, Chuang-Yi |
author_sort | Lee, Hon Man |
collection | PubMed |
description | In the structure of the title compound, [PdCl(2)(C(5)H(5)N)(2)], the Pd(II) atom is located on an inversion centre and the pyridine rings are coplanar. There is intermolecular π–π stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916 (1) Å. The structure is a new polymorph of two previously determined structures [Viossat, Dung & Robert (1993 ▶). Acta Cryst. C49, 84–85; Liao & Lee (2006 ▶). Acta Cryst. E62, m680–m681]. |
format | Text |
id | pubmed-2959498 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29594982010-12-30 A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II) Lee, Hon Man Liao, Chuang-Yi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [PdCl(2)(C(5)H(5)N)(2)], the Pd(II) atom is located on an inversion centre and the pyridine rings are coplanar. There is intermolecular π–π stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916 (1) Å. The structure is a new polymorph of two previously determined structures [Viossat, Dung & Robert (1993 ▶). Acta Cryst. C49, 84–85; Liao & Lee (2006 ▶). Acta Cryst. E62, m680–m681]. International Union of Crystallography 2008-10-22 /pmc/articles/PMC2959498/ /pubmed/21580886 http://dx.doi.org/10.1107/S1600536808033552 Text en © Lee and Liao 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lee, Hon Man Liao, Chuang-Yi A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II) |
title | A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II) |
title_full | A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II) |
title_fullStr | A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II) |
title_full_unstemmed | A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II) |
title_short | A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II) |
title_sort | new monoclinic polymorph of trans-dichloridodipyridinepalladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959498/ https://www.ncbi.nlm.nih.gov/pubmed/21580886 http://dx.doi.org/10.1107/S1600536808033552 |
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