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A new monoclinic polymorph of trans-dichloridodipyridine­palladium(II)

In the structure of the title compound, [PdCl(2)(C(5)H(5)N)(2)], the Pd(II) atom is located on an inversion centre and the pyridine rings are coplanar. There is inter­molecular π–π stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916 (1) Å. The structure is a new polym...

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Autores principales: Lee, Hon Man, Liao, Chuang-Yi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959498/
https://www.ncbi.nlm.nih.gov/pubmed/21580886
http://dx.doi.org/10.1107/S1600536808033552
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author Lee, Hon Man
Liao, Chuang-Yi
author_facet Lee, Hon Man
Liao, Chuang-Yi
author_sort Lee, Hon Man
collection PubMed
description In the structure of the title compound, [PdCl(2)(C(5)H(5)N)(2)], the Pd(II) atom is located on an inversion centre and the pyridine rings are coplanar. There is inter­molecular π–π stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916 (1) Å. The structure is a new polymorph of two previously determined structures [Viossat, Dung & Robert (1993 ▶). Acta Cryst. C49, 84–85; Liao & Lee (2006 ▶). Acta Cryst. E62, m680–m681].
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spelling pubmed-29594982010-12-30 A new monoclinic polymorph of trans-dichloridodipyridine­palladium(II) Lee, Hon Man Liao, Chuang-Yi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [PdCl(2)(C(5)H(5)N)(2)], the Pd(II) atom is located on an inversion centre and the pyridine rings are coplanar. There is inter­molecular π–π stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916 (1) Å. The structure is a new polymorph of two previously determined structures [Viossat, Dung & Robert (1993 ▶). Acta Cryst. C49, 84–85; Liao & Lee (2006 ▶). Acta Cryst. E62, m680–m681]. International Union of Crystallography 2008-10-22 /pmc/articles/PMC2959498/ /pubmed/21580886 http://dx.doi.org/10.1107/S1600536808033552 Text en © Lee and Liao 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lee, Hon Man
Liao, Chuang-Yi
A new monoclinic polymorph of trans-dichloridodipyridine­palladium(II)
title A new monoclinic polymorph of trans-dichloridodipyridine­palladium(II)
title_full A new monoclinic polymorph of trans-dichloridodipyridine­palladium(II)
title_fullStr A new monoclinic polymorph of trans-dichloridodipyridine­palladium(II)
title_full_unstemmed A new monoclinic polymorph of trans-dichloridodipyridine­palladium(II)
title_short A new monoclinic polymorph of trans-dichloridodipyridine­palladium(II)
title_sort new monoclinic polymorph of trans-dichloridodipyridine­palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959498/
https://www.ncbi.nlm.nih.gov/pubmed/21580886
http://dx.doi.org/10.1107/S1600536808033552
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