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(2-Hydroxybenzoato-κO (1))[tris(1-methylbenzimidazol-2-ylmethyl-κN (3))amine-κN]cobalt(II) perchlorate dimethylformamide sesquisolvate
In the title complex, [Co(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·1.5C(3)H(7)NO, the Co(II) ion is five-coordinated by four N atoms from a tris(N-methylbenzimidazol-2-ylmethyl)amine (Mentb) ligand and one O atom from a salicylate ligand in a distorted trigonal–bipyramidal geometry with approximate m...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959500/ https://www.ncbi.nlm.nih.gov/pubmed/21580894 http://dx.doi.org/10.1107/S1600536808033758 |
Sumario: | In the title complex, [Co(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·1.5C(3)H(7)NO, the Co(II) ion is five-coordinated by four N atoms from a tris(N-methylbenzimidazol-2-ylmethyl)amine (Mentb) ligand and one O atom from a salicylate ligand in a distorted trigonal–bipyramidal geometry with approximate molecular C (3) symmetry. The perchlorate ion is disordered over two sites with equal occupancy. One dimethylformamide solvent molecule lies on a general position and is disordered over two coplanar orientations with equal occupancy. A second dimethylformamide molecule is disordered about a twofold rotation axis. There is an intramolecular O—H⋯O hydrogen bond in the cation. |
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