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(2-Hydroxy­benzoato-κO (1))[tris­(1-methyl­benzimidazol-2-ylmethyl-κN (3))amine-κN]cobalt(II) perchlorate dimethyl­formamide sesquisolvate

In the title complex, [Co(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·1.5C(3)H(7)NO, the Co(II) ion is five-coordinated by four N atoms from a tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine (Mentb) ligand and one O atom from a salicylate ligand in a distorted trigonal–bipyramidal geometry with approximate m...

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Detalles Bibliográficos
Autores principales: Fan, Xuyang, Huang, Xingcai, Wang, Kaitong, Sun, Tao, Wu, Huilu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959500/
https://www.ncbi.nlm.nih.gov/pubmed/21580894
http://dx.doi.org/10.1107/S1600536808033758
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author Fan, Xuyang
Huang, Xingcai
Wang, Kaitong
Sun, Tao
Wu, Huilu
author_facet Fan, Xuyang
Huang, Xingcai
Wang, Kaitong
Sun, Tao
Wu, Huilu
author_sort Fan, Xuyang
collection PubMed
description In the title complex, [Co(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·1.5C(3)H(7)NO, the Co(II) ion is five-coordinated by four N atoms from a tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine (Mentb) ligand and one O atom from a salicylate ligand in a distorted trigonal–bipyramidal geometry with approximate mol­ecular C (3) symmetry. The perchlorate ion is disordered over two sites with equal occupancy. One dimethyl­formamide solvent mol­ecule lies on a general position and is disordered over two coplanar orientations with equal occupancy. A second dimethyl­formamide mol­ecule is disordered about a twofold rotation axis. There is an intra­molecular O—H⋯O hydrogen bond in the cation.
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spelling pubmed-29595002010-12-30 (2-Hydroxy­benzoato-κO (1))[tris­(1-methyl­benzimidazol-2-ylmethyl-κN (3))amine-κN]cobalt(II) perchlorate dimethyl­formamide sesquisolvate Fan, Xuyang Huang, Xingcai Wang, Kaitong Sun, Tao Wu, Huilu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·1.5C(3)H(7)NO, the Co(II) ion is five-coordinated by four N atoms from a tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine (Mentb) ligand and one O atom from a salicylate ligand in a distorted trigonal–bipyramidal geometry with approximate mol­ecular C (3) symmetry. The perchlorate ion is disordered over two sites with equal occupancy. One dimethyl­formamide solvent mol­ecule lies on a general position and is disordered over two coplanar orientations with equal occupancy. A second dimethyl­formamide mol­ecule is disordered about a twofold rotation axis. There is an intra­molecular O—H⋯O hydrogen bond in the cation. International Union of Crystallography 2008-10-25 /pmc/articles/PMC2959500/ /pubmed/21580894 http://dx.doi.org/10.1107/S1600536808033758 Text en © Fan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fan, Xuyang
Huang, Xingcai
Wang, Kaitong
Sun, Tao
Wu, Huilu
(2-Hydroxy­benzoato-κO (1))[tris­(1-methyl­benzimidazol-2-ylmethyl-κN (3))amine-κN]cobalt(II) perchlorate dimethyl­formamide sesquisolvate
title (2-Hydroxy­benzoato-κO (1))[tris­(1-methyl­benzimidazol-2-ylmethyl-κN (3))amine-κN]cobalt(II) perchlorate dimethyl­formamide sesquisolvate
title_full (2-Hydroxy­benzoato-κO (1))[tris­(1-methyl­benzimidazol-2-ylmethyl-κN (3))amine-κN]cobalt(II) perchlorate dimethyl­formamide sesquisolvate
title_fullStr (2-Hydroxy­benzoato-κO (1))[tris­(1-methyl­benzimidazol-2-ylmethyl-κN (3))amine-κN]cobalt(II) perchlorate dimethyl­formamide sesquisolvate
title_full_unstemmed (2-Hydroxy­benzoato-κO (1))[tris­(1-methyl­benzimidazol-2-ylmethyl-κN (3))amine-κN]cobalt(II) perchlorate dimethyl­formamide sesquisolvate
title_short (2-Hydroxy­benzoato-κO (1))[tris­(1-methyl­benzimidazol-2-ylmethyl-κN (3))amine-κN]cobalt(II) perchlorate dimethyl­formamide sesquisolvate
title_sort (2-hydroxy­benzoato-κo (1))[tris­(1-methyl­benzimidazol-2-ylmethyl-κn (3))amine-κn]cobalt(ii) perchlorate dimethyl­formamide sesquisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959500/
https://www.ncbi.nlm.nih.gov/pubmed/21580894
http://dx.doi.org/10.1107/S1600536808033758
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