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(2-Hydroxybenzoato-κO (1))[tris(1-methylbenzimidazol-2-ylmethyl-κN (3))amine-κN]cobalt(II) perchlorate dimethylformamide sesquisolvate
In the title complex, [Co(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·1.5C(3)H(7)NO, the Co(II) ion is five-coordinated by four N atoms from a tris(N-methylbenzimidazol-2-ylmethyl)amine (Mentb) ligand and one O atom from a salicylate ligand in a distorted trigonal–bipyramidal geometry with approximate m...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959500/ https://www.ncbi.nlm.nih.gov/pubmed/21580894 http://dx.doi.org/10.1107/S1600536808033758 |
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author | Fan, Xuyang Huang, Xingcai Wang, Kaitong Sun, Tao Wu, Huilu |
author_facet | Fan, Xuyang Huang, Xingcai Wang, Kaitong Sun, Tao Wu, Huilu |
author_sort | Fan, Xuyang |
collection | PubMed |
description | In the title complex, [Co(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·1.5C(3)H(7)NO, the Co(II) ion is five-coordinated by four N atoms from a tris(N-methylbenzimidazol-2-ylmethyl)amine (Mentb) ligand and one O atom from a salicylate ligand in a distorted trigonal–bipyramidal geometry with approximate molecular C (3) symmetry. The perchlorate ion is disordered over two sites with equal occupancy. One dimethylformamide solvent molecule lies on a general position and is disordered over two coplanar orientations with equal occupancy. A second dimethylformamide molecule is disordered about a twofold rotation axis. There is an intramolecular O—H⋯O hydrogen bond in the cation. |
format | Text |
id | pubmed-2959500 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29595002010-12-30 (2-Hydroxybenzoato-κO (1))[tris(1-methylbenzimidazol-2-ylmethyl-κN (3))amine-κN]cobalt(II) perchlorate dimethylformamide sesquisolvate Fan, Xuyang Huang, Xingcai Wang, Kaitong Sun, Tao Wu, Huilu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·1.5C(3)H(7)NO, the Co(II) ion is five-coordinated by four N atoms from a tris(N-methylbenzimidazol-2-ylmethyl)amine (Mentb) ligand and one O atom from a salicylate ligand in a distorted trigonal–bipyramidal geometry with approximate molecular C (3) symmetry. The perchlorate ion is disordered over two sites with equal occupancy. One dimethylformamide solvent molecule lies on a general position and is disordered over two coplanar orientations with equal occupancy. A second dimethylformamide molecule is disordered about a twofold rotation axis. There is an intramolecular O—H⋯O hydrogen bond in the cation. International Union of Crystallography 2008-10-25 /pmc/articles/PMC2959500/ /pubmed/21580894 http://dx.doi.org/10.1107/S1600536808033758 Text en © Fan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fan, Xuyang Huang, Xingcai Wang, Kaitong Sun, Tao Wu, Huilu (2-Hydroxybenzoato-κO (1))[tris(1-methylbenzimidazol-2-ylmethyl-κN (3))amine-κN]cobalt(II) perchlorate dimethylformamide sesquisolvate |
title | (2-Hydroxybenzoato-κO
(1))[tris(1-methylbenzimidazol-2-ylmethyl-κN
(3))amine-κN]cobalt(II) perchlorate dimethylformamide sesquisolvate |
title_full | (2-Hydroxybenzoato-κO
(1))[tris(1-methylbenzimidazol-2-ylmethyl-κN
(3))amine-κN]cobalt(II) perchlorate dimethylformamide sesquisolvate |
title_fullStr | (2-Hydroxybenzoato-κO
(1))[tris(1-methylbenzimidazol-2-ylmethyl-κN
(3))amine-κN]cobalt(II) perchlorate dimethylformamide sesquisolvate |
title_full_unstemmed | (2-Hydroxybenzoato-κO
(1))[tris(1-methylbenzimidazol-2-ylmethyl-κN
(3))amine-κN]cobalt(II) perchlorate dimethylformamide sesquisolvate |
title_short | (2-Hydroxybenzoato-κO
(1))[tris(1-methylbenzimidazol-2-ylmethyl-κN
(3))amine-κN]cobalt(II) perchlorate dimethylformamide sesquisolvate |
title_sort | (2-hydroxybenzoato-κo
(1))[tris(1-methylbenzimidazol-2-ylmethyl-κn
(3))amine-κn]cobalt(ii) perchlorate dimethylformamide sesquisolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959500/ https://www.ncbi.nlm.nih.gov/pubmed/21580894 http://dx.doi.org/10.1107/S1600536808033758 |
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