Cargando…
Di-μ-chlorido-bis{[2-(8-quinolyloxy)acetato-κ(3) N,O (1),O (2)]copper(II)}
The title compound, [Cu(2)(C(11)H(8)NO(3))(2)Cl(2)], is a bicopper(II) complex. Each Cu(II) ion is five-coordinated by two O atoms and one N atom from the (8-quinolyloxy)acetate ligand, and by two μ(2)-chloride ligands, thus exhibiting a distorted square-pyramidal CuCl(2)NO(2) coordination environm...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959508/ https://www.ncbi.nlm.nih.gov/pubmed/21580885 http://dx.doi.org/10.1107/S1600536808031656 |
Sumario: | The title compound, [Cu(2)(C(11)H(8)NO(3))(2)Cl(2)], is a bicopper(II) complex. Each Cu(II) ion is five-coordinated by two O atoms and one N atom from the (8-quinolyloxy)acetate ligand, and by two μ(2)-chloride ligands, thus exhibiting a distorted square-pyramidal CuCl(2)NO(2) coordination environment. Each (8-quinolyloxy)acetate anion acts as a tridentate chelating ligand. In the crystal structure, adjacent quinolyl rings are involved in strong π–π stacking interactions, with interplanar distances of 3.549 (5) and 3.763 (5) Å, thereby forming a two-dimensional planar network perpendicular to the ab plane. Furthermore, a weak interaction [2.750 (4) Å] is observed within these planes between one Cu(II) ion and a carboxylate O atom from a ligand in an adjacent molecule, which also contributes to the stability of the structure. |
---|