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Di-μ-chlorido-bis­{[2-(8-quinol­yloxy)­acetato-κ(3) N,O (1),O (2)]copper(II)}

The title compound, [Cu(2)(C(11)H(8)NO(3))(2)Cl(2)], is a bicopper(II) complex. Each Cu(II) ion is five-coordinated by two O atoms and one N atom from the (8-quinol­yloxy)acetate ligand, and by two μ(2)-chloride ligands, thus exhibiting a distorted square-pyramidal CuCl(2)NO(2) coordination environm...

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Detalles Bibliográficos
Autores principales: Wang, Zhi-hong, Fan, Jun, Zhang, Wei-guang, Wang, Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959508/
https://www.ncbi.nlm.nih.gov/pubmed/21580885
http://dx.doi.org/10.1107/S1600536808031656
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author Wang, Zhi-hong
Fan, Jun
Zhang, Wei-guang
Wang, Jun
author_facet Wang, Zhi-hong
Fan, Jun
Zhang, Wei-guang
Wang, Jun
author_sort Wang, Zhi-hong
collection PubMed
description The title compound, [Cu(2)(C(11)H(8)NO(3))(2)Cl(2)], is a bicopper(II) complex. Each Cu(II) ion is five-coordinated by two O atoms and one N atom from the (8-quinol­yloxy)acetate ligand, and by two μ(2)-chloride ligands, thus exhibiting a distorted square-pyramidal CuCl(2)NO(2) coordination environment. Each (8-quinol­yloxy)acetate anion acts as a tridentate chelating ligand. In the crystal structure, adjacent quinolyl rings are involved in strong π–π stacking inter­actions, with inter­planar distances of 3.549 (5) and 3.763 (5) Å, thereby forming a two-dimensional planar network perpendicular to the ab plane. Furthermore, a weak inter­action [2.750 (4) Å] is observed within these planes between one Cu(II) ion and a carboxyl­ate O atom from a ligand in an adjacent mol­ecule, which also contributes to the stability of the structure.
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spelling pubmed-29595082010-12-30 Di-μ-chlorido-bis­{[2-(8-quinol­yloxy)­acetato-κ(3) N,O (1),O (2)]copper(II)} Wang, Zhi-hong Fan, Jun Zhang, Wei-guang Wang, Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(11)H(8)NO(3))(2)Cl(2)], is a bicopper(II) complex. Each Cu(II) ion is five-coordinated by two O atoms and one N atom from the (8-quinol­yloxy)acetate ligand, and by two μ(2)-chloride ligands, thus exhibiting a distorted square-pyramidal CuCl(2)NO(2) coordination environment. Each (8-quinol­yloxy)acetate anion acts as a tridentate chelating ligand. In the crystal structure, adjacent quinolyl rings are involved in strong π–π stacking inter­actions, with inter­planar distances of 3.549 (5) and 3.763 (5) Å, thereby forming a two-dimensional planar network perpendicular to the ab plane. Furthermore, a weak inter­action [2.750 (4) Å] is observed within these planes between one Cu(II) ion and a carboxyl­ate O atom from a ligand in an adjacent mol­ecule, which also contributes to the stability of the structure. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959508/ /pubmed/21580885 http://dx.doi.org/10.1107/S1600536808031656 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Zhi-hong
Fan, Jun
Zhang, Wei-guang
Wang, Jun
Di-μ-chlorido-bis­{[2-(8-quinol­yloxy)­acetato-κ(3) N,O (1),O (2)]copper(II)}
title Di-μ-chlorido-bis­{[2-(8-quinol­yloxy)­acetato-κ(3) N,O (1),O (2)]copper(II)}
title_full Di-μ-chlorido-bis­{[2-(8-quinol­yloxy)­acetato-κ(3) N,O (1),O (2)]copper(II)}
title_fullStr Di-μ-chlorido-bis­{[2-(8-quinol­yloxy)­acetato-κ(3) N,O (1),O (2)]copper(II)}
title_full_unstemmed Di-μ-chlorido-bis­{[2-(8-quinol­yloxy)­acetato-κ(3) N,O (1),O (2)]copper(II)}
title_short Di-μ-chlorido-bis­{[2-(8-quinol­yloxy)­acetato-κ(3) N,O (1),O (2)]copper(II)}
title_sort di-μ-chlorido-bis­{[2-(8-quinol­yloxy)­acetato-κ(3) n,o (1),o (2)]copper(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959508/
https://www.ncbi.nlm.nih.gov/pubmed/21580885
http://dx.doi.org/10.1107/S1600536808031656
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