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Di-μ-chlorido-bis{[2-(8-quinolyloxy)acetato-κ(3) N,O (1),O (2)]copper(II)}
The title compound, [Cu(2)(C(11)H(8)NO(3))(2)Cl(2)], is a bicopper(II) complex. Each Cu(II) ion is five-coordinated by two O atoms and one N atom from the (8-quinolyloxy)acetate ligand, and by two μ(2)-chloride ligands, thus exhibiting a distorted square-pyramidal CuCl(2)NO(2) coordination environm...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959508/ https://www.ncbi.nlm.nih.gov/pubmed/21580885 http://dx.doi.org/10.1107/S1600536808031656 |
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author | Wang, Zhi-hong Fan, Jun Zhang, Wei-guang Wang, Jun |
author_facet | Wang, Zhi-hong Fan, Jun Zhang, Wei-guang Wang, Jun |
author_sort | Wang, Zhi-hong |
collection | PubMed |
description | The title compound, [Cu(2)(C(11)H(8)NO(3))(2)Cl(2)], is a bicopper(II) complex. Each Cu(II) ion is five-coordinated by two O atoms and one N atom from the (8-quinolyloxy)acetate ligand, and by two μ(2)-chloride ligands, thus exhibiting a distorted square-pyramidal CuCl(2)NO(2) coordination environment. Each (8-quinolyloxy)acetate anion acts as a tridentate chelating ligand. In the crystal structure, adjacent quinolyl rings are involved in strong π–π stacking interactions, with interplanar distances of 3.549 (5) and 3.763 (5) Å, thereby forming a two-dimensional planar network perpendicular to the ab plane. Furthermore, a weak interaction [2.750 (4) Å] is observed within these planes between one Cu(II) ion and a carboxylate O atom from a ligand in an adjacent molecule, which also contributes to the stability of the structure. |
format | Text |
id | pubmed-2959508 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29595082010-12-30 Di-μ-chlorido-bis{[2-(8-quinolyloxy)acetato-κ(3) N,O (1),O (2)]copper(II)} Wang, Zhi-hong Fan, Jun Zhang, Wei-guang Wang, Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(11)H(8)NO(3))(2)Cl(2)], is a bicopper(II) complex. Each Cu(II) ion is five-coordinated by two O atoms and one N atom from the (8-quinolyloxy)acetate ligand, and by two μ(2)-chloride ligands, thus exhibiting a distorted square-pyramidal CuCl(2)NO(2) coordination environment. Each (8-quinolyloxy)acetate anion acts as a tridentate chelating ligand. In the crystal structure, adjacent quinolyl rings are involved in strong π–π stacking interactions, with interplanar distances of 3.549 (5) and 3.763 (5) Å, thereby forming a two-dimensional planar network perpendicular to the ab plane. Furthermore, a weak interaction [2.750 (4) Å] is observed within these planes between one Cu(II) ion and a carboxylate O atom from a ligand in an adjacent molecule, which also contributes to the stability of the structure. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959508/ /pubmed/21580885 http://dx.doi.org/10.1107/S1600536808031656 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Zhi-hong Fan, Jun Zhang, Wei-guang Wang, Jun Di-μ-chlorido-bis{[2-(8-quinolyloxy)acetato-κ(3) N,O (1),O (2)]copper(II)} |
title | Di-μ-chlorido-bis{[2-(8-quinolyloxy)acetato-κ(3)
N,O
(1),O
(2)]copper(II)} |
title_full | Di-μ-chlorido-bis{[2-(8-quinolyloxy)acetato-κ(3)
N,O
(1),O
(2)]copper(II)} |
title_fullStr | Di-μ-chlorido-bis{[2-(8-quinolyloxy)acetato-κ(3)
N,O
(1),O
(2)]copper(II)} |
title_full_unstemmed | Di-μ-chlorido-bis{[2-(8-quinolyloxy)acetato-κ(3)
N,O
(1),O
(2)]copper(II)} |
title_short | Di-μ-chlorido-bis{[2-(8-quinolyloxy)acetato-κ(3)
N,O
(1),O
(2)]copper(II)} |
title_sort | di-μ-chlorido-bis{[2-(8-quinolyloxy)acetato-κ(3)
n,o
(1),o
(2)]copper(ii)} |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959508/ https://www.ncbi.nlm.nih.gov/pubmed/21580885 http://dx.doi.org/10.1107/S1600536808031656 |
work_keys_str_mv | AT wangzhihong dimchloridobis28quinolyloxyacetatok3no1o2copperii AT fanjun dimchloridobis28quinolyloxyacetatok3no1o2copperii AT zhangweiguang dimchloridobis28quinolyloxyacetatok3no1o2copperii AT wangjun dimchloridobis28quinolyloxyacetatok3no1o2copperii |