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Poly[tris­[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thio­cyanato-tricadmium(II)]

The asymmetric unit of the title crystal structure, [Cd(3)(NCS)(6)(C(7)H(6)N(4))(2)](n), contains two independent Cd(II) ions, one of which is located on a crystallographic inversion center. Each independent Cd(II) ion is in a slightly distorted octa­hedral coordination environment, but the disortio...

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Detalles Bibliográficos
Autores principales: Yang, Lin Yan, Shi, Jing Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959520/
https://www.ncbi.nlm.nih.gov/pubmed/21580840
http://dx.doi.org/10.1107/S1600536808032285
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author Yang, Lin Yan
Shi, Jing Min
author_facet Yang, Lin Yan
Shi, Jing Min
author_sort Yang, Lin Yan
collection PubMed
description The asymmetric unit of the title crystal structure, [Cd(3)(NCS)(6)(C(7)H(6)N(4))(2)](n), contains two independent Cd(II) ions, one of which is located on a crystallographic inversion center. Each independent Cd(II) ion is in a slightly distorted octa­hedral coordination environment, but the disortion from ideally octa­hedral is greater in the environment of the Cd(II) ion on a general position. Both thio­cyanate ligands act as bridges connecting independent Cd(II) ions, and the 2-(pyrazol-1-yl)pyrazine ligands chelate one Cd(II) ion in a bidentate mode while the remaining N atom of the pyrazine ring coordinates to a symmetry-related Cd(II) ion, forming a two-dimensional structure parallel to (211).
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spelling pubmed-29595202010-12-30 Poly[tris­[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thio­cyanato-tricadmium(II)] Yang, Lin Yan Shi, Jing Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title crystal structure, [Cd(3)(NCS)(6)(C(7)H(6)N(4))(2)](n), contains two independent Cd(II) ions, one of which is located on a crystallographic inversion center. Each independent Cd(II) ion is in a slightly distorted octa­hedral coordination environment, but the disortion from ideally octa­hedral is greater in the environment of the Cd(II) ion on a general position. Both thio­cyanate ligands act as bridges connecting independent Cd(II) ions, and the 2-(pyrazol-1-yl)pyrazine ligands chelate one Cd(II) ion in a bidentate mode while the remaining N atom of the pyrazine ring coordinates to a symmetry-related Cd(II) ion, forming a two-dimensional structure parallel to (211). International Union of Crystallography 2008-10-11 /pmc/articles/PMC2959520/ /pubmed/21580840 http://dx.doi.org/10.1107/S1600536808032285 Text en © Yang and Shi 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Lin Yan
Shi, Jing Min
Poly[tris­[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thio­cyanato-tricadmium(II)]
title Poly[tris­[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thio­cyanato-tricadmium(II)]
title_full Poly[tris­[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thio­cyanato-tricadmium(II)]
title_fullStr Poly[tris­[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thio­cyanato-tricadmium(II)]
title_full_unstemmed Poly[tris­[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thio­cyanato-tricadmium(II)]
title_short Poly[tris­[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thio­cyanato-tricadmium(II)]
title_sort poly[tris­[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thio­cyanato-tricadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959520/
https://www.ncbi.nlm.nih.gov/pubmed/21580840
http://dx.doi.org/10.1107/S1600536808032285
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