Cargando…
Poly[tris[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thiocyanato-tricadmium(II)]
The asymmetric unit of the title crystal structure, [Cd(3)(NCS)(6)(C(7)H(6)N(4))(2)](n), contains two independent Cd(II) ions, one of which is located on a crystallographic inversion center. Each independent Cd(II) ion is in a slightly distorted octahedral coordination environment, but the disortio...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959520/ https://www.ncbi.nlm.nih.gov/pubmed/21580840 http://dx.doi.org/10.1107/S1600536808032285 |
_version_ | 1782188519207206912 |
---|---|
author | Yang, Lin Yan Shi, Jing Min |
author_facet | Yang, Lin Yan Shi, Jing Min |
author_sort | Yang, Lin Yan |
collection | PubMed |
description | The asymmetric unit of the title crystal structure, [Cd(3)(NCS)(6)(C(7)H(6)N(4))(2)](n), contains two independent Cd(II) ions, one of which is located on a crystallographic inversion center. Each independent Cd(II) ion is in a slightly distorted octahedral coordination environment, but the disortion from ideally octahedral is greater in the environment of the Cd(II) ion on a general position. Both thiocyanate ligands act as bridges connecting independent Cd(II) ions, and the 2-(pyrazol-1-yl)pyrazine ligands chelate one Cd(II) ion in a bidentate mode while the remaining N atom of the pyrazine ring coordinates to a symmetry-related Cd(II) ion, forming a two-dimensional structure parallel to (211). |
format | Text |
id | pubmed-2959520 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29595202010-12-30 Poly[tris[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thiocyanato-tricadmium(II)] Yang, Lin Yan Shi, Jing Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title crystal structure, [Cd(3)(NCS)(6)(C(7)H(6)N(4))(2)](n), contains two independent Cd(II) ions, one of which is located on a crystallographic inversion center. Each independent Cd(II) ion is in a slightly distorted octahedral coordination environment, but the disortion from ideally octahedral is greater in the environment of the Cd(II) ion on a general position. Both thiocyanate ligands act as bridges connecting independent Cd(II) ions, and the 2-(pyrazol-1-yl)pyrazine ligands chelate one Cd(II) ion in a bidentate mode while the remaining N atom of the pyrazine ring coordinates to a symmetry-related Cd(II) ion, forming a two-dimensional structure parallel to (211). International Union of Crystallography 2008-10-11 /pmc/articles/PMC2959520/ /pubmed/21580840 http://dx.doi.org/10.1107/S1600536808032285 Text en © Yang and Shi 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Lin Yan Shi, Jing Min Poly[tris[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thiocyanato-tricadmium(II)] |
title | Poly[tris[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thiocyanato-tricadmium(II)] |
title_full | Poly[tris[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thiocyanato-tricadmium(II)] |
title_fullStr | Poly[tris[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thiocyanato-tricadmium(II)] |
title_full_unstemmed | Poly[tris[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thiocyanato-tricadmium(II)] |
title_short | Poly[tris[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thiocyanato-tricadmium(II)] |
title_sort | poly[tris[μ(2)-2-(pyrazol-1-yl)pyrazine]hexa-μ(1,3)-thiocyanato-tricadmium(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959520/ https://www.ncbi.nlm.nih.gov/pubmed/21580840 http://dx.doi.org/10.1107/S1600536808032285 |
work_keys_str_mv | AT yanglinyan polytrism22pyrazol1ylpyrazinehexam13thiocyanatotricadmiumii AT shijingmin polytrism22pyrazol1ylpyrazinehexam13thiocyanatotricadmiumii |