Bis[μ-2-(3-pyridylmeth­yl)-2H-benzo­triazole]bis­[nitratosilver(I)]

In the title centrosymmetric binuclear Ag(I) complex, [Ag(2)(NO(3))(2)(C(12)H(10)N(4))(2)], each Ag(I) center is coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 2-(3-pyridylmeth­yl)-2H-benzotriazole (L) ligands, and an O atom of a coordinated NO(3) (−) anion i...

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Detalles Bibliográficos
Autores principales: Hu, Min, Ma, Song-Tao, Guo, Liang-Qi, Sun, Guang-Hui, Fang, Shao-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959521/
https://www.ncbi.nlm.nih.gov/pubmed/21580908
http://dx.doi.org/10.1107/S160053680803479X
Descripción
Sumario:In the title centrosymmetric binuclear Ag(I) complex, [Ag(2)(NO(3))(2)(C(12)H(10)N(4))(2)], each Ag(I) center is coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 2-(3-pyridylmeth­yl)-2H-benzotriazole (L) ligands, and an O atom of a coordinated NO(3) (−) anion in a distorted T-shaped geometry. This forms a unique box-like cyclic dimer with an intra­molecular non-bonding Ag⋯Ag separation of 6.327 (2) Å. Weak inter­molecular Ag⋯O(nitrate) inter­actions [2.728 (4) and 2.646 (3) Å] link the binuclear units, forming a two-dimensional network parallel to (100). Inter­molecular C—H⋯O hydrogen-bonding inter­actions, involving the L ligands and the coordinated NO(3) (−) anions, link the sheets, forming a three-dimensional framework.

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