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Bis[μ-2-(3-pyridylmethyl)-2H-benzotriazole]bis[nitratosilver(I)]
In the title centrosymmetric binuclear Ag(I) complex, [Ag(2)(NO(3))(2)(C(12)H(10)N(4))(2)], each Ag(I) center is coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 2-(3-pyridylmethyl)-2H-benzotriazole (L) ligands, and an O atom of a coordinated NO(3) (−) anion i...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959521/ https://www.ncbi.nlm.nih.gov/pubmed/21580908 http://dx.doi.org/10.1107/S160053680803479X |
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author | Hu, Min Ma, Song-Tao Guo, Liang-Qi Sun, Guang-Hui Fang, Shao-Ming |
author_facet | Hu, Min Ma, Song-Tao Guo, Liang-Qi Sun, Guang-Hui Fang, Shao-Ming |
author_sort | Hu, Min |
collection | PubMed |
description | In the title centrosymmetric binuclear Ag(I) complex, [Ag(2)(NO(3))(2)(C(12)H(10)N(4))(2)], each Ag(I) center is coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 2-(3-pyridylmethyl)-2H-benzotriazole (L) ligands, and an O atom of a coordinated NO(3) (−) anion in a distorted T-shaped geometry. This forms a unique box-like cyclic dimer with an intramolecular non-bonding Ag⋯Ag separation of 6.327 (2) Å. Weak intermolecular Ag⋯O(nitrate) interactions [2.728 (4) and 2.646 (3) Å] link the binuclear units, forming a two-dimensional network parallel to (100). Intermolecular C—H⋯O hydrogen-bonding interactions, involving the L ligands and the coordinated NO(3) (−) anions, link the sheets, forming a three-dimensional framework. |
format | Text |
id | pubmed-2959521 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29595212010-12-30 Bis[μ-2-(3-pyridylmethyl)-2H-benzotriazole]bis[nitratosilver(I)] Hu, Min Ma, Song-Tao Guo, Liang-Qi Sun, Guang-Hui Fang, Shao-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric binuclear Ag(I) complex, [Ag(2)(NO(3))(2)(C(12)H(10)N(4))(2)], each Ag(I) center is coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 2-(3-pyridylmethyl)-2H-benzotriazole (L) ligands, and an O atom of a coordinated NO(3) (−) anion in a distorted T-shaped geometry. This forms a unique box-like cyclic dimer with an intramolecular non-bonding Ag⋯Ag separation of 6.327 (2) Å. Weak intermolecular Ag⋯O(nitrate) interactions [2.728 (4) and 2.646 (3) Å] link the binuclear units, forming a two-dimensional network parallel to (100). Intermolecular C—H⋯O hydrogen-bonding interactions, involving the L ligands and the coordinated NO(3) (−) anions, link the sheets, forming a three-dimensional framework. International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959521/ /pubmed/21580908 http://dx.doi.org/10.1107/S160053680803479X Text en © Hu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hu, Min Ma, Song-Tao Guo, Liang-Qi Sun, Guang-Hui Fang, Shao-Ming Bis[μ-2-(3-pyridylmethyl)-2H-benzotriazole]bis[nitratosilver(I)] |
title | Bis[μ-2-(3-pyridylmethyl)-2H-benzotriazole]bis[nitratosilver(I)] |
title_full | Bis[μ-2-(3-pyridylmethyl)-2H-benzotriazole]bis[nitratosilver(I)] |
title_fullStr | Bis[μ-2-(3-pyridylmethyl)-2H-benzotriazole]bis[nitratosilver(I)] |
title_full_unstemmed | Bis[μ-2-(3-pyridylmethyl)-2H-benzotriazole]bis[nitratosilver(I)] |
title_short | Bis[μ-2-(3-pyridylmethyl)-2H-benzotriazole]bis[nitratosilver(I)] |
title_sort | bis[μ-2-(3-pyridylmethyl)-2h-benzotriazole]bis[nitratosilver(i)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959521/ https://www.ncbi.nlm.nih.gov/pubmed/21580908 http://dx.doi.org/10.1107/S160053680803479X |
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