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Bis[μ-2-(3-pyridylmeth­yl)-2H-benzo­triazole]bis­[nitratosilver(I)]

In the title centrosymmetric binuclear Ag(I) complex, [Ag(2)(NO(3))(2)(C(12)H(10)N(4))(2)], each Ag(I) center is coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 2-(3-pyridylmeth­yl)-2H-benzotriazole (L) ligands, and an O atom of a coordinated NO(3) (−) anion i...

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Autores principales: Hu, Min, Ma, Song-Tao, Guo, Liang-Qi, Sun, Guang-Hui, Fang, Shao-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959521/
https://www.ncbi.nlm.nih.gov/pubmed/21580908
http://dx.doi.org/10.1107/S160053680803479X
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author Hu, Min
Ma, Song-Tao
Guo, Liang-Qi
Sun, Guang-Hui
Fang, Shao-Ming
author_facet Hu, Min
Ma, Song-Tao
Guo, Liang-Qi
Sun, Guang-Hui
Fang, Shao-Ming
author_sort Hu, Min
collection PubMed
description In the title centrosymmetric binuclear Ag(I) complex, [Ag(2)(NO(3))(2)(C(12)H(10)N(4))(2)], each Ag(I) center is coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 2-(3-pyridylmeth­yl)-2H-benzotriazole (L) ligands, and an O atom of a coordinated NO(3) (−) anion in a distorted T-shaped geometry. This forms a unique box-like cyclic dimer with an intra­molecular non-bonding Ag⋯Ag separation of 6.327 (2) Å. Weak inter­molecular Ag⋯O(nitrate) inter­actions [2.728 (4) and 2.646 (3) Å] link the binuclear units, forming a two-dimensional network parallel to (100). Inter­molecular C—H⋯O hydrogen-bonding inter­actions, involving the L ligands and the coordinated NO(3) (−) anions, link the sheets, forming a three-dimensional framework.
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spelling pubmed-29595212010-12-30 Bis[μ-2-(3-pyridylmeth­yl)-2H-benzo­triazole]bis­[nitratosilver(I)] Hu, Min Ma, Song-Tao Guo, Liang-Qi Sun, Guang-Hui Fang, Shao-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric binuclear Ag(I) complex, [Ag(2)(NO(3))(2)(C(12)H(10)N(4))(2)], each Ag(I) center is coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 2-(3-pyridylmeth­yl)-2H-benzotriazole (L) ligands, and an O atom of a coordinated NO(3) (−) anion in a distorted T-shaped geometry. This forms a unique box-like cyclic dimer with an intra­molecular non-bonding Ag⋯Ag separation of 6.327 (2) Å. Weak inter­molecular Ag⋯O(nitrate) inter­actions [2.728 (4) and 2.646 (3) Å] link the binuclear units, forming a two-dimensional network parallel to (100). Inter­molecular C—H⋯O hydrogen-bonding inter­actions, involving the L ligands and the coordinated NO(3) (−) anions, link the sheets, forming a three-dimensional framework. International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959521/ /pubmed/21580908 http://dx.doi.org/10.1107/S160053680803479X Text en © Hu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hu, Min
Ma, Song-Tao
Guo, Liang-Qi
Sun, Guang-Hui
Fang, Shao-Ming
Bis[μ-2-(3-pyridylmeth­yl)-2H-benzo­triazole]bis­[nitratosilver(I)]
title Bis[μ-2-(3-pyridylmeth­yl)-2H-benzo­triazole]bis­[nitratosilver(I)]
title_full Bis[μ-2-(3-pyridylmeth­yl)-2H-benzo­triazole]bis­[nitratosilver(I)]
title_fullStr Bis[μ-2-(3-pyridylmeth­yl)-2H-benzo­triazole]bis­[nitratosilver(I)]
title_full_unstemmed Bis[μ-2-(3-pyridylmeth­yl)-2H-benzo­triazole]bis­[nitratosilver(I)]
title_short Bis[μ-2-(3-pyridylmeth­yl)-2H-benzo­triazole]bis­[nitratosilver(I)]
title_sort bis[μ-2-(3-pyridylmeth­yl)-2h-benzo­triazole]bis­[nitratosilver(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959521/
https://www.ncbi.nlm.nih.gov/pubmed/21580908
http://dx.doi.org/10.1107/S160053680803479X
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