(Z)-4-[3-(3-Oxoquinuclidin-2-ylidene­meth­yl)-1H-indol-1-ylmeth­yl]benzo­nitrile

The title compound, C(24)H(21)N(3)O, was prepared by the reaction of (Z)-2-(1H-indol-3-ylmethyl­ene)-1-aza­bicyclo­[2.2.2]octan-3-one with α-bromo-p-toluonitrile, under phase-transfer catalytic (PTC) conditions using triethyl­benzyl­ammonium chloride and 50% w/v aqueous NaOH solution in dichloro­met...

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Detalles Bibliográficos
Autores principales: Reddy, Thirupathi Reddy Yerram, Penthala, Narsimha Reddy, Parkin, Sean, Crooks, Peter A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959535/
https://www.ncbi.nlm.nih.gov/pubmed/21580917
http://dx.doi.org/10.1107/S1600536808030006
Descripción
Sumario:The title compound, C(24)H(21)N(3)O, was prepared by the reaction of (Z)-2-(1H-indol-3-ylmethyl­ene)-1-aza­bicyclo­[2.2.2]octan-3-one with α-bromo-p-toluonitrile, under phase-transfer catalytic (PTC) conditions using triethyl­benzyl­ammonium chloride and 50% w/v aqueous NaOH solution in dichloro­methane. The crystal structure indicates the presence of a double bond with Z geometry connecting the aza­bicyclic and indole groups.

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