Di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(II)dizinc(II) N,N′-dimethyl­formamide disolvate

The title compound, [Pb(2)Zn(2)(C(22)H(18)N(2)O(4))(2)Cl(4)]·2C(3)H(7)NO, was synthesized using a step-by-step method and has a slipped sandwich configuration. The coordination environment of the Zn(2+) ion is distorted square-pyramidal and it is coordinated by N(2)O(2) of the Schiff base ligand and...

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Detalles Bibliográficos
Autores principales: Wang, Hailong, Zhang, Daopeng, Zhang, Li-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959539/
https://www.ncbi.nlm.nih.gov/pubmed/21580858
http://dx.doi.org/10.1107/S1600536808032704
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author Wang, Hailong
Zhang, Daopeng
Zhang, Li-Fang
author_facet Wang, Hailong
Zhang, Daopeng
Zhang, Li-Fang
author_sort Wang, Hailong
collection PubMed
description The title compound, [Pb(2)Zn(2)(C(22)H(18)N(2)O(4))(2)Cl(4)]·2C(3)H(7)NO, was synthesized using a step-by-step method and has a slipped sandwich configuration. The coordination environment of the Zn(2+) ion is distorted square-pyramidal and it is coordinated by N(2)O(2) of the Schiff base ligand and chloride; each Pb(2+) ion is coordinated by the four 6,6′-dimeth­oxy-2,2′-[o-phenyl­ene­bis(nitrilo­methyl­idyne)]diphenolate (L) O atoms and two chloride ions. The Zn(II)Pb(II) dinuclear unit, through an inversion-symmetry operation, forms a tetra­meric complex with double chloride bridges.
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spelling pubmed-29595392010-12-30 Di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(II)dizinc(II) N,N′-dimethyl­formamide disolvate Wang, Hailong Zhang, Daopeng Zhang, Li-Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pb(2)Zn(2)(C(22)H(18)N(2)O(4))(2)Cl(4)]·2C(3)H(7)NO, was synthesized using a step-by-step method and has a slipped sandwich configuration. The coordination environment of the Zn(2+) ion is distorted square-pyramidal and it is coordinated by N(2)O(2) of the Schiff base ligand and chloride; each Pb(2+) ion is coordinated by the four 6,6′-dimeth­oxy-2,2′-[o-phenyl­ene­bis(nitrilo­methyl­idyne)]diphenolate (L) O atoms and two chloride ions. The Zn(II)Pb(II) dinuclear unit, through an inversion-symmetry operation, forms a tetra­meric complex with double chloride bridges. International Union of Crystallography 2008-10-15 /pmc/articles/PMC2959539/ /pubmed/21580858 http://dx.doi.org/10.1107/S1600536808032704 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Hailong
Zhang, Daopeng
Zhang, Li-Fang
Di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(II)dizinc(II) N,N′-dimethyl­formamide disolvate
title Di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(II)dizinc(II) N,N′-dimethyl­formamide disolvate
title_full Di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(II)dizinc(II) N,N′-dimethyl­formamide disolvate
title_fullStr Di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(II)dizinc(II) N,N′-dimethyl­formamide disolvate
title_full_unstemmed Di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(II)dizinc(II) N,N′-dimethyl­formamide disolvate
title_short Di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(II)dizinc(II) N,N′-dimethyl­formamide disolvate
title_sort di-μ-chlorido-dichlorido-bis{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}dilead(ii)dizinc(ii) n,n′-dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959539/
https://www.ncbi.nlm.nih.gov/pubmed/21580858
http://dx.doi.org/10.1107/S1600536808032704
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AT zhangdaopeng dimchloridodichloridobism66dimethoxy22ophenylenebisnitrilomethylidynediphenolatodileadiidizinciinndimethylformamidedisolvate
AT zhanglifang dimchloridodichloridobism66dimethoxy22ophenylenebisnitrilomethylidynediphenolatodileadiidizinciinndimethylformamidedisolvate

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