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Bis(1,10-phenanthroline-κ(2) N,N′)(phenyl­acetato-κO)copper(II) phenyl­acetate hexa­hydrate

In the title compound, [Cu(C(8)H(7)O(2))(C(12)H(8)N(2))(2)](C(8)H(7)O(2))·6H(2)O, the Cu atom is in a distorted square-pyramidal coordination environment. The six crystallographically independent uncoordinated water mol­ecules are inter­connected by hydrogen bonds, completing dodeca­water (H(2)O)(12...

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Detalles Bibliográficos
Autores principales: Tu, Bing-Tian, Xie, Hong-Zhen, Ren, Ying-Tao, Chen, Jing-Zhong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959544/
https://www.ncbi.nlm.nih.gov/pubmed/21580909
http://dx.doi.org/10.1107/S1600536808032480
Descripción
Sumario:In the title compound, [Cu(C(8)H(7)O(2))(C(12)H(8)N(2))(2)](C(8)H(7)O(2))·6H(2)O, the Cu atom is in a distorted square-pyramidal coordination environment. The six crystallographically independent uncoordinated water mol­ecules are inter­connected by hydrogen bonds, completing dodeca­water (H(2)O)(12) clusters which are hydrogen bonded to the carboxyl­ate groups of phenyl­acetate anions, building up one-dimensional anionic chains propagating along [100]. Between the cationic and anionic chains are hydrogen bonds from water mol­ecules to the carboxyl­ate O atoms belonging to the phenyl­acetato ligands.