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Bis(1,10-phenanthroline-κ(2) N,N′)(phenyl­acetato-κO)copper(II) phenyl­acetate hexa­hydrate

In the title compound, [Cu(C(8)H(7)O(2))(C(12)H(8)N(2))(2)](C(8)H(7)O(2))·6H(2)O, the Cu atom is in a distorted square-pyramidal coordination environment. The six crystallographically independent uncoordinated water mol­ecules are inter­connected by hydrogen bonds, completing dodeca­water (H(2)O)(12...

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Autores principales: Tu, Bing-Tian, Xie, Hong-Zhen, Ren, Ying-Tao, Chen, Jing-Zhong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959544/
https://www.ncbi.nlm.nih.gov/pubmed/21580909
http://dx.doi.org/10.1107/S1600536808032480
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author Tu, Bing-Tian
Xie, Hong-Zhen
Ren, Ying-Tao
Chen, Jing-Zhong
author_facet Tu, Bing-Tian
Xie, Hong-Zhen
Ren, Ying-Tao
Chen, Jing-Zhong
author_sort Tu, Bing-Tian
collection PubMed
description In the title compound, [Cu(C(8)H(7)O(2))(C(12)H(8)N(2))(2)](C(8)H(7)O(2))·6H(2)O, the Cu atom is in a distorted square-pyramidal coordination environment. The six crystallographically independent uncoordinated water mol­ecules are inter­connected by hydrogen bonds, completing dodeca­water (H(2)O)(12) clusters which are hydrogen bonded to the carboxyl­ate groups of phenyl­acetate anions, building up one-dimensional anionic chains propagating along [100]. Between the cationic and anionic chains are hydrogen bonds from water mol­ecules to the carboxyl­ate O atoms belonging to the phenyl­acetato ligands.
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spelling pubmed-29595442010-12-30 Bis(1,10-phenanthroline-κ(2) N,N′)(phenyl­acetato-κO)copper(II) phenyl­acetate hexa­hydrate Tu, Bing-Tian Xie, Hong-Zhen Ren, Ying-Tao Chen, Jing-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(8)H(7)O(2))(C(12)H(8)N(2))(2)](C(8)H(7)O(2))·6H(2)O, the Cu atom is in a distorted square-pyramidal coordination environment. The six crystallographically independent uncoordinated water mol­ecules are inter­connected by hydrogen bonds, completing dodeca­water (H(2)O)(12) clusters which are hydrogen bonded to the carboxyl­ate groups of phenyl­acetate anions, building up one-dimensional anionic chains propagating along [100]. Between the cationic and anionic chains are hydrogen bonds from water mol­ecules to the carboxyl­ate O atoms belonging to the phenyl­acetato ligands. International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959544/ /pubmed/21580909 http://dx.doi.org/10.1107/S1600536808032480 Text en © Tu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tu, Bing-Tian
Xie, Hong-Zhen
Ren, Ying-Tao
Chen, Jing-Zhong
Bis(1,10-phenanthroline-κ(2) N,N′)(phenyl­acetato-κO)copper(II) phenyl­acetate hexa­hydrate
title Bis(1,10-phenanthroline-κ(2) N,N′)(phenyl­acetato-κO)copper(II) phenyl­acetate hexa­hydrate
title_full Bis(1,10-phenanthroline-κ(2) N,N′)(phenyl­acetato-κO)copper(II) phenyl­acetate hexa­hydrate
title_fullStr Bis(1,10-phenanthroline-κ(2) N,N′)(phenyl­acetato-κO)copper(II) phenyl­acetate hexa­hydrate
title_full_unstemmed Bis(1,10-phenanthroline-κ(2) N,N′)(phenyl­acetato-κO)copper(II) phenyl­acetate hexa­hydrate
title_short Bis(1,10-phenanthroline-κ(2) N,N′)(phenyl­acetato-κO)copper(II) phenyl­acetate hexa­hydrate
title_sort bis(1,10-phenanthroline-κ(2) n,n′)(phenyl­acetato-κo)copper(ii) phenyl­acetate hexa­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959544/
https://www.ncbi.nlm.nih.gov/pubmed/21580909
http://dx.doi.org/10.1107/S1600536808032480
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