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Bis(1,10-phenanthroline-κ(2) N,N′)(phenylacetato-κO)copper(II) phenylacetate hexahydrate
In the title compound, [Cu(C(8)H(7)O(2))(C(12)H(8)N(2))(2)](C(8)H(7)O(2))·6H(2)O, the Cu atom is in a distorted square-pyramidal coordination environment. The six crystallographically independent uncoordinated water molecules are interconnected by hydrogen bonds, completing dodecawater (H(2)O)(12...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959544/ https://www.ncbi.nlm.nih.gov/pubmed/21580909 http://dx.doi.org/10.1107/S1600536808032480 |
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author | Tu, Bing-Tian Xie, Hong-Zhen Ren, Ying-Tao Chen, Jing-Zhong |
author_facet | Tu, Bing-Tian Xie, Hong-Zhen Ren, Ying-Tao Chen, Jing-Zhong |
author_sort | Tu, Bing-Tian |
collection | PubMed |
description | In the title compound, [Cu(C(8)H(7)O(2))(C(12)H(8)N(2))(2)](C(8)H(7)O(2))·6H(2)O, the Cu atom is in a distorted square-pyramidal coordination environment. The six crystallographically independent uncoordinated water molecules are interconnected by hydrogen bonds, completing dodecawater (H(2)O)(12) clusters which are hydrogen bonded to the carboxylate groups of phenylacetate anions, building up one-dimensional anionic chains propagating along [100]. Between the cationic and anionic chains are hydrogen bonds from water molecules to the carboxylate O atoms belonging to the phenylacetato ligands. |
format | Text |
id | pubmed-2959544 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29595442010-12-30 Bis(1,10-phenanthroline-κ(2) N,N′)(phenylacetato-κO)copper(II) phenylacetate hexahydrate Tu, Bing-Tian Xie, Hong-Zhen Ren, Ying-Tao Chen, Jing-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(8)H(7)O(2))(C(12)H(8)N(2))(2)](C(8)H(7)O(2))·6H(2)O, the Cu atom is in a distorted square-pyramidal coordination environment. The six crystallographically independent uncoordinated water molecules are interconnected by hydrogen bonds, completing dodecawater (H(2)O)(12) clusters which are hydrogen bonded to the carboxylate groups of phenylacetate anions, building up one-dimensional anionic chains propagating along [100]. Between the cationic and anionic chains are hydrogen bonds from water molecules to the carboxylate O atoms belonging to the phenylacetato ligands. International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959544/ /pubmed/21580909 http://dx.doi.org/10.1107/S1600536808032480 Text en © Tu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tu, Bing-Tian Xie, Hong-Zhen Ren, Ying-Tao Chen, Jing-Zhong Bis(1,10-phenanthroline-κ(2) N,N′)(phenylacetato-κO)copper(II) phenylacetate hexahydrate |
title | Bis(1,10-phenanthroline-κ(2)
N,N′)(phenylacetato-κO)copper(II) phenylacetate hexahydrate |
title_full | Bis(1,10-phenanthroline-κ(2)
N,N′)(phenylacetato-κO)copper(II) phenylacetate hexahydrate |
title_fullStr | Bis(1,10-phenanthroline-κ(2)
N,N′)(phenylacetato-κO)copper(II) phenylacetate hexahydrate |
title_full_unstemmed | Bis(1,10-phenanthroline-κ(2)
N,N′)(phenylacetato-κO)copper(II) phenylacetate hexahydrate |
title_short | Bis(1,10-phenanthroline-κ(2)
N,N′)(phenylacetato-κO)copper(II) phenylacetate hexahydrate |
title_sort | bis(1,10-phenanthroline-κ(2)
n,n′)(phenylacetato-κo)copper(ii) phenylacetate hexahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959544/ https://www.ncbi.nlm.nih.gov/pubmed/21580909 http://dx.doi.org/10.1107/S1600536808032480 |
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