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Tris[μ-1,2-bis(diphenylphosphino)ethane]-1:2κ(2) P:P′;1:3κ(2) P:P′;2:3κ(2) P:P′-di-μ-bromido-1:2κ(4) Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate
In the crystal structure of the title compound, [Cu(3)Br(3)(C(26)H(24)P(2))(3)]·0.5CH(3)COCH(3), two of the Cu centers are bridged by two bromide anions forming a Cu(μ-Br)(2)Cu core, which is further bridged by a 1,2-bis(diphenylphosphino)ethane (dppe) ligand. The third Cu center is terminally bo...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959548/ https://www.ncbi.nlm.nih.gov/pubmed/21580860 http://dx.doi.org/10.1107/S1600536808032789 |
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author | Shi, Wen-Juan |
author_facet | Shi, Wen-Juan |
author_sort | Shi, Wen-Juan |
collection | PubMed |
description | In the crystal structure of the title compound, [Cu(3)Br(3)(C(26)H(24)P(2))(3)]·0.5CH(3)COCH(3), two of the Cu centers are bridged by two bromide anions forming a Cu(μ-Br)(2)Cu core, which is further bridged by a 1,2-bis(diphenylphosphino)ethane (dppe) ligand. The third Cu center is terminally bound to another bromide ligand and is connected to the other two Cu atoms by bridging dppe ligands, forming a triangular cluster unit. The acetone solvent molecule exhibits twofold disorder about an inversion centre at ([Image: see text], 1, 0). The crystal structure is stabilized by intermolecular C—H⋯Br hydrogen bonds. |
format | Text |
id | pubmed-2959548 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29595482010-12-30 Tris[μ-1,2-bis(diphenylphosphino)ethane]-1:2κ(2) P:P′;1:3κ(2) P:P′;2:3κ(2) P:P′-di-μ-bromido-1:2κ(4) Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate Shi, Wen-Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(3)Br(3)(C(26)H(24)P(2))(3)]·0.5CH(3)COCH(3), two of the Cu centers are bridged by two bromide anions forming a Cu(μ-Br)(2)Cu core, which is further bridged by a 1,2-bis(diphenylphosphino)ethane (dppe) ligand. The third Cu center is terminally bound to another bromide ligand and is connected to the other two Cu atoms by bridging dppe ligands, forming a triangular cluster unit. The acetone solvent molecule exhibits twofold disorder about an inversion centre at ([Image: see text], 1, 0). The crystal structure is stabilized by intermolecular C—H⋯Br hydrogen bonds. International Union of Crystallography 2008-10-15 /pmc/articles/PMC2959548/ /pubmed/21580860 http://dx.doi.org/10.1107/S1600536808032789 Text en © Wen-Juan Shi 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shi, Wen-Juan Tris[μ-1,2-bis(diphenylphosphino)ethane]-1:2κ(2) P:P′;1:3κ(2) P:P′;2:3κ(2) P:P′-di-μ-bromido-1:2κ(4) Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate |
title | Tris[μ-1,2-bis(diphenylphosphino)ethane]-1:2κ(2)
P:P′;1:3κ(2)
P:P′;2:3κ(2)
P:P′-di-μ-bromido-1:2κ(4)
Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate |
title_full | Tris[μ-1,2-bis(diphenylphosphino)ethane]-1:2κ(2)
P:P′;1:3κ(2)
P:P′;2:3κ(2)
P:P′-di-μ-bromido-1:2κ(4)
Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate |
title_fullStr | Tris[μ-1,2-bis(diphenylphosphino)ethane]-1:2κ(2)
P:P′;1:3κ(2)
P:P′;2:3κ(2)
P:P′-di-μ-bromido-1:2κ(4)
Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate |
title_full_unstemmed | Tris[μ-1,2-bis(diphenylphosphino)ethane]-1:2κ(2)
P:P′;1:3κ(2)
P:P′;2:3κ(2)
P:P′-di-μ-bromido-1:2κ(4)
Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate |
title_short | Tris[μ-1,2-bis(diphenylphosphino)ethane]-1:2κ(2)
P:P′;1:3κ(2)
P:P′;2:3κ(2)
P:P′-di-μ-bromido-1:2κ(4)
Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate |
title_sort | tris[μ-1,2-bis(diphenylphosphino)ethane]-1:2κ(2)
p:p′;1:3κ(2)
p:p′;2:3κ(2)
p:p′-di-μ-bromido-1:2κ(4)
br:br-bromido-3κbr-tricopper(i) acetone hemisolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959548/ https://www.ncbi.nlm.nih.gov/pubmed/21580860 http://dx.doi.org/10.1107/S1600536808032789 |
work_keys_str_mv | AT shiwenjuan trism12bisdiphenylphosphinoethane12k2pp13k2pp23k2ppdimbromido12k4brbrbromido3kbrtricopperiacetonehemisolvate |