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Tris[μ-1,2-bis­(diphenyl­phosphino)­ethane]-1:2κ(2) P:P′;1:3κ(2) P:P′;2:3κ(2) P:P′-di-μ-bromido-1:2κ(4) Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate

In the crystal structure of the title compound, [Cu(3)Br(3)(C(26)H(24)P(2))(3)]·0.5CH(3)COCH(3), two of the Cu centers are bridged by two bromide anions forming a Cu(μ-Br)(2)Cu core, which is further bridged by a 1,2-bis­(diphenyl­phosphino)­ethane (dppe) ligand. The third Cu center is terminally bo...

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Autor principal: Shi, Wen-Juan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959548/
https://www.ncbi.nlm.nih.gov/pubmed/21580860
http://dx.doi.org/10.1107/S1600536808032789
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author Shi, Wen-Juan
author_facet Shi, Wen-Juan
author_sort Shi, Wen-Juan
collection PubMed
description In the crystal structure of the title compound, [Cu(3)Br(3)(C(26)H(24)P(2))(3)]·0.5CH(3)COCH(3), two of the Cu centers are bridged by two bromide anions forming a Cu(μ-Br)(2)Cu core, which is further bridged by a 1,2-bis­(diphenyl­phosphino)­ethane (dppe) ligand. The third Cu center is terminally bound to another bromide ligand and is connected to the other two Cu atoms by bridging dppe ligands, forming a triangular cluster unit. The acetone solvent mol­ecule exhibits twofold disorder about an inversion centre at ([Image: see text], 1, 0). The crystal structure is stabilized by inter­molecular C—H⋯Br hydrogen bonds.
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spelling pubmed-29595482010-12-30 Tris[μ-1,2-bis­(diphenyl­phosphino)­ethane]-1:2κ(2) P:P′;1:3κ(2) P:P′;2:3κ(2) P:P′-di-μ-bromido-1:2κ(4) Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate Shi, Wen-Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(3)Br(3)(C(26)H(24)P(2))(3)]·0.5CH(3)COCH(3), two of the Cu centers are bridged by two bromide anions forming a Cu(μ-Br)(2)Cu core, which is further bridged by a 1,2-bis­(diphenyl­phosphino)­ethane (dppe) ligand. The third Cu center is terminally bound to another bromide ligand and is connected to the other two Cu atoms by bridging dppe ligands, forming a triangular cluster unit. The acetone solvent mol­ecule exhibits twofold disorder about an inversion centre at ([Image: see text], 1, 0). The crystal structure is stabilized by inter­molecular C—H⋯Br hydrogen bonds. International Union of Crystallography 2008-10-15 /pmc/articles/PMC2959548/ /pubmed/21580860 http://dx.doi.org/10.1107/S1600536808032789 Text en © Wen-Juan Shi 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Wen-Juan
Tris[μ-1,2-bis­(diphenyl­phosphino)­ethane]-1:2κ(2) P:P′;1:3κ(2) P:P′;2:3κ(2) P:P′-di-μ-bromido-1:2κ(4) Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate
title Tris[μ-1,2-bis­(diphenyl­phosphino)­ethane]-1:2κ(2) P:P′;1:3κ(2) P:P′;2:3κ(2) P:P′-di-μ-bromido-1:2κ(4) Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate
title_full Tris[μ-1,2-bis­(diphenyl­phosphino)­ethane]-1:2κ(2) P:P′;1:3κ(2) P:P′;2:3κ(2) P:P′-di-μ-bromido-1:2κ(4) Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate
title_fullStr Tris[μ-1,2-bis­(diphenyl­phosphino)­ethane]-1:2κ(2) P:P′;1:3κ(2) P:P′;2:3κ(2) P:P′-di-μ-bromido-1:2κ(4) Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate
title_full_unstemmed Tris[μ-1,2-bis­(diphenyl­phosphino)­ethane]-1:2κ(2) P:P′;1:3κ(2) P:P′;2:3κ(2) P:P′-di-μ-bromido-1:2κ(4) Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate
title_short Tris[μ-1,2-bis­(diphenyl­phosphino)­ethane]-1:2κ(2) P:P′;1:3κ(2) P:P′;2:3κ(2) P:P′-di-μ-bromido-1:2κ(4) Br:Br-bromido-3κBr-tricopper(I) acetone hemisolvate
title_sort tris[μ-1,2-bis­(diphenyl­phosphino)­ethane]-1:2κ(2) p:p′;1:3κ(2) p:p′;2:3κ(2) p:p′-di-μ-bromido-1:2κ(4) br:br-bromido-3κbr-tricopper(i) acetone hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959548/
https://www.ncbi.nlm.nih.gov/pubmed/21580860
http://dx.doi.org/10.1107/S1600536808032789
work_keys_str_mv AT shiwenjuan trism12bisdiphenylphosphinoethane12k2pp13k2pp23k2ppdimbromido12k4brbrbromido3kbrtricopperiacetonehemisolvate