Di-μ-bromido-bis­[bromido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)mercury(II)]

The asymmetric unit of the title compound, [Hg(2)Br(4)(C(12)H(12)N(2))(2)], contains one half-mol­ecule. The Hg(II) atom is five-coordinated in a trigonal–bipyramidal configuration by two N atoms from the chelating 4,4′-dimethyl-2,2′-bipyridine ligand, two bridging Br and one terminal Br atom, leadi...

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Autores principales: Kalateh, Khadijeh, Ebadi, Amin, Ahmadi, Roya, Amani, Vahid, Khavasi, Hamid Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959555/
https://www.ncbi.nlm.nih.gov/pubmed/21580848
http://dx.doi.org/10.1107/S1600536808032510
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author Kalateh, Khadijeh
Ebadi, Amin
Ahmadi, Roya
Amani, Vahid
Khavasi, Hamid Reza
author_facet Kalateh, Khadijeh
Ebadi, Amin
Ahmadi, Roya
Amani, Vahid
Khavasi, Hamid Reza
author_sort Kalateh, Khadijeh
collection PubMed
description The asymmetric unit of the title compound, [Hg(2)Br(4)(C(12)H(12)N(2))(2)], contains one half-mol­ecule. The Hg(II) atom is five-coordinated in a trigonal–bipyramidal configuration by two N atoms from the chelating 4,4′-dimethyl-2,2′-bipyridine ligand, two bridging Br and one terminal Br atom, leading to a centrosymmetric dimeric mol­ecule. There is a π–π contact between the pyridine rings [centroid-to-centroid distance = 3.756 (5) Å].
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spelling pubmed-29595552010-12-30 Di-μ-bromido-bis­[bromido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)mercury(II)] Kalateh, Khadijeh Ebadi, Amin Ahmadi, Roya Amani, Vahid Khavasi, Hamid Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Hg(2)Br(4)(C(12)H(12)N(2))(2)], contains one half-mol­ecule. The Hg(II) atom is five-coordinated in a trigonal–bipyramidal configuration by two N atoms from the chelating 4,4′-dimethyl-2,2′-bipyridine ligand, two bridging Br and one terminal Br atom, leading to a centrosymmetric dimeric mol­ecule. There is a π–π contact between the pyridine rings [centroid-to-centroid distance = 3.756 (5) Å]. International Union of Crystallography 2008-10-15 /pmc/articles/PMC2959555/ /pubmed/21580848 http://dx.doi.org/10.1107/S1600536808032510 Text en © Kalateh et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kalateh, Khadijeh
Ebadi, Amin
Ahmadi, Roya
Amani, Vahid
Khavasi, Hamid Reza
Di-μ-bromido-bis­[bromido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)mercury(II)]
title Di-μ-bromido-bis­[bromido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)mercury(II)]
title_full Di-μ-bromido-bis­[bromido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)mercury(II)]
title_fullStr Di-μ-bromido-bis­[bromido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)mercury(II)]
title_full_unstemmed Di-μ-bromido-bis­[bromido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)mercury(II)]
title_short Di-μ-bromido-bis­[bromido(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)mercury(II)]
title_sort di-μ-bromido-bis­[bromido(4,4′-dimethyl-2,2′-bipyridine-κ(2) n,n′)mercury(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959555/
https://www.ncbi.nlm.nih.gov/pubmed/21580848
http://dx.doi.org/10.1107/S1600536808032510
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AT ahmadiroya dimbromidobisbromido44dimethyl22bipyridinek2nnmercuryii
AT amanivahid dimbromidobisbromido44dimethyl22bipyridinek2nnmercuryii
AT khavasihamidreza dimbromidobisbromido44dimethyl22bipyridinek2nnmercuryii

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