Cargando…
Bis(2,2′-bipyridine-κ(2) N,N′)(croconato-κ(2) O,O′)nickel(II)
The title compound, [Ni(C(5)O(5))(C(10)H(8)N(2))(2)], lies across a crystallographic twofold axis, around which two 2,2′-bipyridine (2,2′-bipy) ligands are arranged in a propeller manner. The local geometry of the NiN(4)O(2) coordination core basically adopts an octahedral geometry. The molecular...
| Autores principales: | , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959560/ https://www.ncbi.nlm.nih.gov/pubmed/21580897 http://dx.doi.org/10.1107/S1600536808033771 |
| _version_ | 1782188528898146304 |
|---|---|
| author | Chen, Hong-Feng Fang, Qi Yu, Wen-Tao |
| author_facet | Chen, Hong-Feng Fang, Qi Yu, Wen-Tao |
| author_sort | Chen, Hong-Feng |
| collection | PubMed |
| description | The title compound, [Ni(C(5)O(5))(C(10)H(8)N(2))(2)], lies across a crystallographic twofold axis, around which two 2,2′-bipyridine (2,2′-bipy) ligands are arranged in a propeller manner. The local geometry of the NiN(4)O(2) coordination core basically adopts an octahedral geometry. The molecular twofold axis is along the direction of the molecular dipole moment, and the complex is packed with its dipole moment alternately along the +b and −b directions. The crystal structure is stabilized by intermolecular C—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-2959560 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29595602010-12-30 Bis(2,2′-bipyridine-κ(2) N,N′)(croconato-κ(2) O,O′)nickel(II) Chen, Hong-Feng Fang, Qi Yu, Wen-Tao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(5)O(5))(C(10)H(8)N(2))(2)], lies across a crystallographic twofold axis, around which two 2,2′-bipyridine (2,2′-bipy) ligands are arranged in a propeller manner. The local geometry of the NiN(4)O(2) coordination core basically adopts an octahedral geometry. The molecular twofold axis is along the direction of the molecular dipole moment, and the complex is packed with its dipole moment alternately along the +b and −b directions. The crystal structure is stabilized by intermolecular C—H⋯O hydrogen bonds. International Union of Crystallography 2008-10-25 /pmc/articles/PMC2959560/ /pubmed/21580897 http://dx.doi.org/10.1107/S1600536808033771 Text en © Chen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Hong-Feng Fang, Qi Yu, Wen-Tao Bis(2,2′-bipyridine-κ(2) N,N′)(croconato-κ(2) O,O′)nickel(II) |
| title | Bis(2,2′-bipyridine-κ(2)
N,N′)(croconato-κ(2)
O,O′)nickel(II) |
| title_full | Bis(2,2′-bipyridine-κ(2)
N,N′)(croconato-κ(2)
O,O′)nickel(II) |
| title_fullStr | Bis(2,2′-bipyridine-κ(2)
N,N′)(croconato-κ(2)
O,O′)nickel(II) |
| title_full_unstemmed | Bis(2,2′-bipyridine-κ(2)
N,N′)(croconato-κ(2)
O,O′)nickel(II) |
| title_short | Bis(2,2′-bipyridine-κ(2)
N,N′)(croconato-κ(2)
O,O′)nickel(II) |
| title_sort | bis(2,2′-bipyridine-κ(2)
n,n′)(croconato-κ(2)
o,o′)nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959560/ https://www.ncbi.nlm.nih.gov/pubmed/21580897 http://dx.doi.org/10.1107/S1600536808033771 |
| work_keys_str_mv | AT chenhongfeng bis22bipyridinek2nncroconatok2oonickelii AT fangqi bis22bipyridinek2nncroconatok2oonickelii AT yuwentao bis22bipyridinek2nncroconatok2oonickelii |